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Sort & Refine Home > Bath > Bath Rugs & Mats > Top Rated Products in Bath Rugs & Mats Refine Store availability Sort Best sellers Best match Price: low to high Price: high to low Highest rating New Sort: New Best sellers Best match Price: low to high Price: high to low Highest rating New $8.29 List price $9.44 Save $1.15 Drive Medical Bathtub Shower Mat 5.0 stars 4.8667 (45) ratings Free shipping on orders over $50 Free store pickup Rollback from $21.56 - $34.50 Traditional Nylon 2-Piece Washable Bathroom Rug Set 4.5 stars 4.6667 (12) ratings Free shipping on orders over $50 Free store pickup Only at Walmart from $22.39 - $24.12 Better Homes and Gardens Extra Soft Bath 3-Piece Set 4.5 stars 4.5395 (228) ratings Free shipping on orders over $50 Free store pickup today from $56.94 - $74.00 Finest Luxury Ultra Plush Nylon 3-Piece Washable Bathroom Rug Set 5.0 stars 5.0 (3) ratings Free shipping Free store pickup Best Seller from $5.00 - $34.56 Better Homes and Gardens Extra Soft Bath Rug 4.5 stars 4.5 (300) ratings Free shipping on orders over $50 Free store pickup today Rollback from $12.99 - $15.36 SlipX Solutions Soft Touch Bath Mat 4.0 stars 3.9 (10) ratings Free shipping on orders over $50 Free store pickup $11.44 AC 19.5" x 29.5" Wipe Your Paws Flocked Coir Doormat 5.0 stars 5.0 (6) ratings Free shipping on orders over $50 Free store pickup today Rollback from $26.04 - $35.00 Pebbles Bath Rug Runner, Khaki 4.5 stars 4.4074 (27) ratings Free shipping on orders over $50 Free store pickup Only at Walmart $13.96 Mainstays Chevron Bath Rug, Yellow 4.5 stars 4.32 (25) ratings Free shipping on orders over $50 Free store pickup today Clearance from $12.00 - $24.40 Springmaid My Finest Nylon Bath Rug Collection 4.5 stars 4.6 (5) ratings Free shipping on orders over $50 Free store pickup from $27.48 - $48.00 Finest Luxury Ultra Plush Nylon Washable Bath Rug 4.0 stars 4.2 (5) ratings Free shipping on orders over $50 Free store pickup Rollback $11.50 Deluxe Bath Mat, Clear 4.5 stars 4.513 (115) ratings Free shipping on orders over $50 Free store pickup Rollback from $48.76 - $55.00 Fashion Street Extra-Long Memory Foam Bath Rug, 1'8" x 5'4" 4.5 stars 4.3529 (17) ratings Free shipping Free store pickup Only at Walmart from $9.45 - $14.97 Better Homes and Gardens Thick and Plush Bath Collection, Contour 5.0 stars 4.8 (5) ratings Free shipping on orders over $50 Free store pickup today Clearance from $9.98 - $33.69 InterDesign Formbu Bath Floor Mat Collection 4.0 stars 3.9048 (21) ratings Free shipping on orders over $50 Free store pickup Rollback $14.88 Airia Basics Deluxe Quick-Dry Tub Mat, Aqua 4.0 stars 4.0 (5) ratings Free shipping on orders over $50 Free store pickup today Rollback from $31.41 - $45.23 Cabernet Nylon 3-Piece Washable Bathroom Rug Set 5.0 stars 5.0 (2) ratings Free shipping on orders over $50 Free store pickup Only at Walmart $14.88 Better Homes and Gardens Texas Horse Tufted Bath Rug 3.0 stars 3.0 (2) ratings Free shipping on orders over $50 Free store pickup today Rollback from $17.84 - $36.60 Traditional Plush Nylon Washable Bath Rug 5.0 stars 5.0 (4) ratings Free shipping on orders over $50 Free store pickup Only at Walmart $6.96 Mainstays Rubber Bath Mat, Mineral Blue 4.0 stars 4.0714 (14) ratings Free shipping on orders over $50 Free store pickup $13.40 Con-Tact Brand Circles Rubber Bath Mat, 2' x 1'2" 4.5 stars 4.6667 (6) ratings Sold & Shipped by Toolboxsupply from $32.87 - $43.00 Traditional Nylon 3-Piece Washable Bathroom Rug Set 5.0 stars 4.8 (10) ratings Free shipping on orders over $50 Free store pickup Only at Walmart $14.88 Better Homes and Gardens Owl Memory Foam Bath Rug, 20" x 30" 4.5 stars 4.25 (4) ratings Free shipping on orders over $50 Free store pickup today Clearance from $5.62 - $14.96 Con-Tact Brand Pebble PVC Bath Mat 4.0 stars 3.8333 (6) ratings Free shipping Free store pickup Rollback from $12.99 - $14.54 SlipX Solutions Essential Round Shower Mat 4.5 stars 4.5 (6) ratings Free shipping on orders over $50 Free store pickup Only at Walmart from $25.50 - $28.14 Somerset Home 2-Piece Memory Foam Bath Mat Set 4.5 stars 4.4 (10) ratings Free shipping on orders over $50 Free store pickup from $22.58 - $46.06 Serendipity Shaggy Nylon Washable Bath Rug 4.5 stars 4.375 (8) ratings Free shipping on orders over $50 Free store pickup Clearance from $12.88 - $16.88 Better Homes and Gardens Memory Foam Bath Collection 4.5 stars 4.5031 (163) ratings Free shipping on orders over $50 Free store pickup today Rollback from $6.80 - $7.59 Rubbermaid Medium Rubber Bath Mat, White 4.5 stars 4.3396 (106) ratings Free shipping on orders over $50 Free store pickup Rollback from $31.60 - $35.96 Pebbles 2pc Bath Rug Set 4.5 stars 4.3214 (28) ratings Free shipping on orders over $50 Free store pickup Rollback from $5.84 - $6.78 Con-Tact Brand Pebble PVC Shower Mat 4.0 stars 4.0 (1) ratings Free shipping on orders over $50 Free store pickup from $36.40 - $54.00 Serendipity Shaggy Nylon 3-Piece Washable Bathroom Rug Set 4.5 stars 4.2727 (11) ratings Free shipping on orders over $50 Free store pickup Only at Walmart from $8.50 - $17.00 Better Homes and Gardens Extra Soft Chevron Bath Rug 4.5 stars 4.5 (6) ratings Free shipping on orders over $50 Free store pickup Rollback from $10.98 - $27.99 Lux 100 Percent Cotton Bath Rug 4.0 stars 4.0 (1) ratings Free shipping Free store pickup Only at Walmart $12.96 Mainstays Droplets Vinyl Bath Mat, Clear 4.0 stars 4.0 (2) ratings Free shipping on orders over $50 Free store pickup today Rollback from $13.37 - $23.00 Made Here Fret Pattern Bath Rug Collection 4.0 stars 3.75 (8) ratings Free shipping on orders over $50 Free store pickup $18.99 Shower Mat Clear 4.5 stars 4.6 (10) ratings Sold & Shipped by Miles Kimball Company $6.35 Con-Tact Brand Bubble PVC Shower Mat, Clear, 1'9" x 1'9" 2.5 stars 2.3333 (3) ratings Free shipping on orders over $50 Free store pickup from $33.16 - $47.00 Jazz Shaggy Nylon 3-Piece Washable Bathroom Rug Set 4.5 stars 4.5714 (14) ratings Free shipping Free store pickup Rollback from $22.02 - $33.00 Queen Cotton Runner Washable Bath Rug 3.5 stars 3.7143 (7) ratings Free shipping on orders over $50 Free store pickup 1 2 1 2 Next Browse Related Products Bath Mats Bathroom Rug Runners Bathroom Runners Tub and Shower Treads Bath Rugs & Mats Bath Rug Runners Clear Done Sort New Best sellers Best match Price: low to high Price: high to low Highest rating New Departments Home Bath Decor Shipping & Pickup
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[Investigation of Colorectal Cancer Cases among Patients Aged over 75 Years Who Received Postoperative Adjuvant Chemotherapy]. - PubMed - NCBI
1 selected item: 30765657
Gan To Kagaku Ryoho. 2019 Jan;46(1):109-111.
[Investigation of Colorectal Cancer Cases among Patients Aged over 75 Years Who Received Postoperative Adjuvant Chemotherapy].
Shimokuni T1, Yabe S, Okumura K, Konishi Y, Nakagawa T, Nishikawa M, Takahashi M.
Dept. of Surgery, JCHO Sapporo Hokushin Medical Hospital.
As the aging of the Japanese population progresses, the administration of postoperative adjuvant chemotherapy( AC)to the elderly is also expected to increase.
To examine the characteristics of AC in cases of colorectal cancer among elderly people aged over 75 years.
Forty-eight cases of colorectal cancer patients who received AC.
The clinicopathological factors, including 14 patient-related factors, 6 operation-related factors, and 2 AC-related factors, as well as the long-term outcomes, were compared between the elderly group of patients aged over 75 years(group O, 12 cases)and the non-elderly group(group Y, 36 cases).
Significant differences were observed between groups in neutrophil count(p=0.044), operation time(p=0.044), AC regimen(p=0.006), and administration completion status (p=0.046). Compared to group Y, a higher proportion of oral drug alone(92% vs 39%)and completion rate of the initial setting dose(75% vs 39%)were observed in group O. There was no significant difference in the 2-year disease-free survival rate.
Oral preparations of AC may be useful from the viewpoint of tolerability in the elderly.
30765657

type: global

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text: Popular right now in Toronto (ON) Quality Suites Toronto Airport Hotel 262 Carlingview Drive Non-Smoking Two Double Suite booked 1 hour, 6 minutes, 48 seconds ago Comfort Inn Toronto North Hotel 66 Norfinch Drive North Smoking Comfort Care Double Room booked 1 hour, 36 minutes, 48 seconds ago Bond Place Hotel 65 Dundas Street East Standard Twin Room booked 3 hours, 11 minutes, 48 seconds ago Five great reasons to book with us!

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160 Pcs Tibetan silver bali style hollow dolphin charms Pendants 19 20mm TS532 | eBay Please enable JavaScript Our new search experience requires JavaScript to be enabled. Please enable JavaScript on your browser, then try again.
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New Lorenz Genuine Soft Leather Ladies Cross Body/ Shoulder Bag 1941 Small | eBay Skip to main content eBay Shop by category Enter your search keyword All Categories Advanced or register':' style="margin-right:3px">Hello -User-.'.replace(/-User-/,escape(a)))+"")}catch(b){document.write("")}})();Hello (Sign in to bid or buy)Daily DealsCollections My eBayExpand My eBay Summary Bids/Offers Watch List Wish List All Lists Purchase History Selling My Collections Followed Searches Messages Collect & Spend Learn more SellExpand Sell Sell an item Seller centre International selling Seller protection Seller Fees Sell for Charity CommunityExpand Community Answer Centre Discussion Boards Groups News Help & ContactExpand Help & Contact Contact Us (Phone / Chat / E-mail) FAQs Delivery & Returns Ask the eBay Community Resolution Centre Back to home page
Details about New Lorenz Genuine Soft Leather Ladies Cross Body/ Shoulder Bag 1941 Small Please check given dimensions before purchasing
New Lorenz Genuine Soft Leather Ladies Cross Body/ Shoulder Bag 1941 Small |
420085589504
LADIES LEATHER CROSS BODY... £7.25
LADIES REAL LEATHER CROSS BODY... £5.95
New Ladies Real Leather Satchel... £8.50
28 Oct, 2014 12:20:03 GMT View all revisions
Product FeaturesSoft genuine leather cross body bag from well known brand LorenzPerfect size for all your valuables and other essential itemsTwo main compartments are accessed by two zips on the top of the bagTwo further pockets on the front of the bag securely fastened with zipsStrap is fully adjustable allowing the bag to be worn both across the body and over the shoulderMaximum strap length - 119cm (47")Exact Dimensions -17cm x 17cm x 5cmPlease note that actual colours may vary slightly from those shown on your screenLorenz Accessories is a world wide brand that is renowned for producing a wide variety of leather goods at affordable prices. They use a variety of leathers and techniques allowing them to create excellent value for money items such as leather; bags, rucksacks, bumbags, purses and wallets, to name but a few.
Estimated by Fri. 31 Oct. to the UK per eBay FAST & FREE £5.99


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jamin05 - Member Forum Posts - TripAdvisor
Profile Badge collection Travel map jamin05 Send Message Since Feb 2005Virginia
13 Forum Posts jamin05's TripCollective Progress Total Points 260 New ReviewerThis badge is earned after 1 review.Write a ReviewNew PhotographerThis badge is earned after 1 photo.Add a PhotoReviewerThis badge is earned after 3 reviews.Write a ReviewHelpful ReviewerThis badge is earned after 1 helpful vote.Write a ReviewReadershipThis badge is earned after a reviewer has 100 readers.Write a ReviewHotel Expert Level 1The Hotel Expert badge levels up after every three hotel reviews.Level 1: earned after your 3rd hotel review.Write a ReviewLuxury Hotel Expert Level 1The Luxury Hotel Expert badge levels up after every three luxury hotel reviews.Level 1: earned after your 3rd luxury hotel review.Write a ReviewBoutique Hotel Expert Level 1The Boutique Hotel Expert badge levels up after every three boutique hotel reviews.Level 1: earned after your 3rd boutique hotel review.Write a ReviewB&B and Inns Expert Level 1The B&B and Inns Expert badge levels up after every three B&B or Inn reviews.Level 1: earned after your 3rd B&B or Inn review.Write a ReviewResort Expert Level 1The Resort Expert badge levels up after every three resort reviews.Level 1: earned after your 3rd resort review.Write a ReviewRestaurant Expert Level 1The Restaurant Expert badge levels up after every three restaurant reviews.Level 1: earned after your 3rd restaurant review.Write a ReviewAttraction Expert Level 1The Attraction Expert badge levels up after every three attraction reviews.Level 1: earned after your 3rd attraction review.Write a ReviewSenior ReviewerThis badge is earned after 5 reviews.Write a ReviewContributorThis badge is earned after 10 reviews.Write a ReviewSenior ContributorThis badge is earned after 20 reviews.Write a ReviewTop ContributorThis badge is earned after 50 reviews.Write a Review
How do I earn points? Every time you contribute to TripAdvisor, you earn TripCollective points. Here’s a list of what you can contribute, and how much it’s worth. Review 100points Photo 30points Video 30points Forum Post 20points Rating 5points Traveler Article Creation 100points Traveler Article Edits 5points Trip Lists 50points Helpful Vote 1point Earn points, reach new levels. The more points you earn, the higher your level – and the more you’re recognized in the travel community for your contributions. Your TripCollective level appears in your traveler profile. Level6 10000points Level5 5000points Level4 2500points Level3 1000points Level2 500points Level1 300points Total Points 260jamin05's Contributions Forum Posts (13)DateTypeForumTopicPointsApr 29, 2005ReplyOcho RiosSan Souci April 30 To May 720Apr 26, 2005ReplyOcho RiosAny one going to SGOR April 30th-May7th??20Apr 26, 2005ReplyOcho RiosSan Souci April 30 To May 720Apr 17, 2005TopicOcho RiosSGOR maner villa emnities20Apr 2, 2005ReplyOcho Riossgor in room movies20Apr 2, 2005TopicOcho RiosGolf at sgor20Mar 30, 2005TopicOcho Riossgor in room movies20Mar 2, 2005ReplyOcho RiosSGOR rooms..20Feb 21, 2005ReplyRoanokeholiday inn. tabglewood.20Feb 21, 2005ReplyVirginiavirginia or north carolina?20Feb 21, 2005ReplyBar HarborHow far is Bangor to Bar Harbor??20Feb 21, 2005ReplyOcho RiosSandals Grande Ocho Rios20Feb 21, 2005ReplyOcho RiosSandals Grande Ocho Rios20PreviousNext1Bonus points are available on occasion across the site. Keep an eye out for opportunities to get extra points!

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Being There (Audiobook) by Erica Komisar, Sydny Miner | Audible.com
By: Erica Komisar, Sydny Miner
4.5 out of 5 stars 27,837
How to establish emotional connection with a newborn or young child - regardless of whether you're able to pause your career to stay home
How to select and train quality childcare if necessary - and how to ease transitions and minimize stress for your baby or toddler
What's true and false about widely held beliefs like "babies are resilient" and how to combat feelings of post-partum depression or boredom
Why three months of maternity leave is not long enough - and how women and their partners can take control of their choices to provide for their family's emotional needs in the first three years
©2017 Erica Komisar (P)2017 HighBridge, a division of Recorded Books
I was hesitant to listen to this book because I felt that I somehow was a not a good mom for working outside the home. however the book encourages if you can take a leave of absence from the workforce to go for it. she does not scold mothers who work, she understands that many households today are 2income. she describes how mothers can be more emotionally present with their children, selecting caregivers, the impact on kids when mothers are not there emotionally and physically. this book made me be more aware how I have not been emotionally present with my kids and how that stems from my relationship with my mother. it has made me change for the better.

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Bella House: 2020 Room Prices , Deals & Reviews | Expedia
Bella House, Copenhagen Bella House, Copenhagen
Popular LocationBella Center3 min walk
Popular LocationRoyal Arena17 min walk
AirportCopenhagen (CPH-Kastrup)9 min drive
Popular LocationNy Carlsberg Glyptotek12 min drive
1238-sq-foot room with courtyard views
This apartment is located in Copenhagen's Amager neighborhood. Copenhagen Opera House and National Museum of Denmark are cultural highlights, and some of the area's popular attractions include Tivoli Gardens and Copenhagen Zoo. Looking to enjoy an event or a game? See what's going on at Royal Arena or Parken Stadium.
Bella Center - 3 min walk
Royal Arena - 17 min walk
National Museum of Denmark - 13 min drive
Ørestad Station - 13 min walk
3.5-star Copenhagen apartments in Amager, walk to Bella Center
This smoke-free apartment building features self parking and laundry facilities. The apartment provides a kitchen with a refrigerator, an oven, a stovetop, and a microwave. Guests can appreciate conveniences like a washer/dryer and a dining area, and other amenities include free WiFi and a sitting area.
Guest accommodations at this apartment offer washers/dryers and coffee/tea makers. These individually decorated and furnished accommodations have separate sitting areas. Accommodations at this 3.5-star apartment have kitchens with refrigerators, stovetops, microwaves, and separate dining areas. Bathrooms include showers and hair dryers.
This Copenhagen apartment provides complimentary wireless Internet access. Smart televisions are featured in guestrooms. Additionally, rooms include irons/ironing boards and blackout drapes/curtains.
Bella House Apartment
Bella House Copenhagen
Bella House Apartment Copenhagen
Can I cancel my reservation for free at Bella House and receive a full refund?
Yes, Bella House offers free cancellation on select room rates, because flexibility matters! Please refer to Bella House cancellation policy on our site for more details about any exclusions or requirements.
Self parking is available for DKK 150 per day.
Located in Amager, this apartment building is within 1 mi (2 km) of Field's Shopping Centre, Bella Center, and Royal Arena. Koncerthuset and Islands Brygge Harbour Baths are also within 3 mi (5 km). Bella Center Station is 10 minutes by foot and Ørestad Station is 13 minutes.

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Victorian Tea Tickets, Sat, May 10, 2014 at 1:00 PM | Eventbrite
Children's Fairy and Gnome Homes
Children's Fairy and Gnome Figures
Denver Museum of Miniatures, Dolls and Toy, Denver
Saturday, May 10, 2014 from 1:00 PM to 3:00 PM (MDT)
Denver Museum of Miniatures, Dolls and Toys Member
Enjoy a relaxing and unique tea experience and with scones, tea sandwiches, and desserts which are artfully prepared for you, along with two tea varieties, served by Four Mile Volunteers in full Victorian-era costume. Bring a friend and share a relaxing afternoon, harkening back to a simpler era when teatime was for indulging and socializing. A special presentation by the Denver Museum of Miniatures, Dolls, & Toys on Victorian era dolls and toys will highlight the afternoon.
Advance purchase required by 4pm, Thurs., May 8.
The entire event, tea and presentation, will last 2 hours with the tea-service being 45 minutes.
Tables will be decorated and include a party favor for each guest.
Please note that all tickets are will-call only, non-refundable, and non-transferable. All online ticket purchases will be processed by Blacktie-Colorado.com, a secure, online merchant service. You will receive immediate confirmation of your purchase from eventbrite.com, our secure service, with a follow-up e-mail or phone call from us directly within 2 business days regarding the status of your order. The Grant Family Education Center, where this event is held, is fully accessible by wheelchair. Please contact museum staff for any special accommodations you may require.
Have questions about Victorian Tea? Contact Four Mile Historic Park

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"I have a new generalization of logical relations that can prove SN for CiC (...), including the full universe hierarchy and inductive types." : typesjump to contentmy subredditsannouncementsArtAskRedditaskscienceawwblogbookscreepydataisbeautifulDIYDocumentariesEarthPornexplainlikeimfiveFitnessfoodfunnyFuturologygadgetsgamingGetMotivatedgifshistoryIAmAInternetIsBeautifulJokesLifeProTipslistentothismildlyinterestingmoviesMusicnewsnosleepnottheonionOldSchoolCoolpersonalfinancephilosophyphotoshopbattlespicsscienceShowerthoughtsspacesportstelevisiontifutodayilearnedTwoXChromosomesUpliftingNewsvideosworldnewsWritingPromptsedit subscriptionsfront-all-random | gadgets-Futurology-todayilearned-space-books-philosophy-gifs-funny-AskReddit-Art-GetMotivated-videos-history-nosleep-dataisbeautiful-explainlikeimfive-WritingPrompts-UpliftingNews-news-creepy-worldnews-Jokes-food-movies-Fitness-science-listentothis-tifu-television-aww-DIY-Documentaries-Showerthoughts-LifeProTips-TwoXChromosomes-EarthPorn-photoshopbattles-pics-gaming-mildlyinteresting-IAmA-InternetIsBeautiful-personalfinance-Music-nottheonion-askscience-sports-OldSchoolCoolmore » typescommentsrelatedother discussions (1)want to join? login or register in seconds|Englishlimit my search to /r/typesuse the following search parameters to narrow your results:subreddit:subredditfind submissions in "subreddit"author:usernamefind submissions by "username"site:example.comfind submissions from "example.com"url:textsearch for "text" in urlselftext:textsearch for "text" in self post contentsself:yes (or self:no)include (or exclude) self postsnsfw:yes (or nsfw:no)include (or exclude) results marked as NSFWe.g. subreddit:aww site:imgur.com dogsee the search faq for details.advanced search: by author, subreddit...this post was submitted on 22 Nov 201116 points (95% upvoted)shortlink: remember mereset passwordloginSubmit a new linkSubmit a new text posttypessubscribeunsubscribe2,782 readers~4 users here nowa community for 6 yearsmessage the moderatorsMODERATORSjapple151617"I have a new generalization of logical relations that can prove SN for CiC (...), including the full universe hierarchy and inductive types." (cs.rice.edu)submitted 2 years ago by gallais1 commentsharecancelsorry, this has been archived and can no longer be voted onloading...all 1 commentssorted by: controversialbesttopnewhotcontroversialoldrandom[–]gallais[S] 2 points3 points4 points 2 years ago (0 children)sorry, this has been archived and can no longer be voted onAnd the corresponding email
username:try anotheravailable!account recovery email: (optional)we only send email at your requestpassword:verify password:remember mecreate accountis it really that easy? only one way to find out...loginalready have an account and just want to login?username:password:remember merecover passwordloginclose this windowinterface languageEnglish [en]العربية [ar]Беларуская мова [be]български език [bg]Bosanski [bs]català [ca]česky [cs]dansk [da]Deutsch [de]Ελληνικά [el]English (Australia) [en-au]English (Canadian) [en-ca]English (Great Britain) [en-gb]English [en-us]Esperanto [eo]español [es]español [es-ar]eesti keel [et]Euskara [eu]فارسی [fa]suomi [fi]français [fr]Gàidhlig [gd]עברית [he]मानक हिन्दी [hi]hrvatski [hr]Magyar [hu]Հայերեն լեզու [hy]Bahasa Indonesia [id]íslenska [is] (*)italiano (Italy) [it]日本語 [ja]ಕನ್ನಡ [kn_IN]한국어 [ko]Latin [la]1337 [leet]LOL [lol]lietuvių kalba [lt]latviešu valoda [lv]Nederlands [nl]Nynorsk [nn]Norsk [no]Arrrrrrrr! [pir]polski [pl]português [pt] (*)português [pt-pt]português brasileiro [pt_BR]română [ro]русский [ru]slovenčina [sk]slovenščina [sl]српски језик [sr]Srpski [sr-la]Svenska [sv]தமிழ் [ta]ภาษาไทย [th]Türkçe [tr]українська мова [uk]Tiếng Việt [vi]中文 [zh] (*) incomplete volunteer to translateπ Rendered by PID 24452 on app-01 at 2014-09-18 15:06:05.121916+00:00 running eabe34e country code: US.

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Nucleotide Links for PubMed (Select 9763455) - Nucleotide - NCBI
SpeciesClearAnimals(4)Fungi(2)Customize ...Molecule typesCleargenomic DNA/RNA(2)mRNA(4)Customize ...Source databasesClearINSDC (GenBank)(3)RefSeq(3)Customize ...Sequence lengthclear
Select item 11008542441.Schizosaccharomyces pombe zinc finger protein (ZPR1) gene, complete cds3,199 bp linear DNA Accession: AF019768.2 GI: 1100854244 GenBankFASTAGraphicsSelect item 9525562662.Homo sapiens ZPR1 zinc finger (ZPR1), transcript variant 2, mRNA2,019 bp linear mRNA Accession: NM_001317086.1 GI: 952556266 GenBankFASTAGraphicsSelect item 9525562653.Homo sapiens ZPR1 zinc finger (ZPR1), transcript variant 1, mRNA2,181 bp linear mRNA Accession: NM_003904.4 GI: 952556265 GenBankFASTAGraphicsSelect item 1337789424.Mus musculus ZPR1 zinc finger (Zpr1), mRNA2,984 bp linear mRNA Accession: NM_011752.2 GI: 133778942 GenBankFASTAGraphicsSelect item 35104655.Saccharomyces cerevisiae zinc finger protein (ZPR1) gene, complete cds2,798 bp linear DNA Accession: AF019769.1 GI: 3510465 GenBankFASTAGraphicsSelect item 35104616.Homo sapiens zinc finger protein (ZPR1) mRNA, complete cds1,817 bp linear mRNA Accession: AF019767.1 GI: 3510461 GenBankFASTAGraphics
db=nuccore|term=|query=1|qty=4|blobid=NCID_1_11727545_130.14.22.215_9001_1498373469_1443950529_0MetA0_S_MegaStore_F_1|ismultiple=false|min_list=5|max_list=20|def_tree=20|def_list=|def_view=|url=/Taxonomy/backend/subset.cgi?|trace_url=/stat?
Turn Off Turn On Nucleotide Links for PubMed (Select 9763455) (6)


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list pagerank blogs within Design Elements
There are 4 results about list pagerank blogs within Design Elements
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Patent US5382434 - Low steroid dose dry pharmaceutical preparation - Google PatentsSearch Images Maps Play YouTube News Gmail Drive More »Sign inPatentsDisclosed are dry pharmaceutical preparations containing potent steroidal medicinal agents in combination with an excipient capable of binding the agent to an extent greater than 80% and a having a demixing potential of less than 10% for said agent. Such excipients include spray-dried polyalcohols, granulated...http://www.google.com/patents/US5382434?utm_source=gb-gplus-sharePatent US5382434 - Low steroid dose dry pharmaceutical preparationAdvanced Patent SearchPublication numberUS5382434 APublication typeGrantApplication numberUS 08/216,236Publication dateJan 17, 1995Filing dateMar 22, 1994Priority dateMar 12, 1991Fee statusPaidAlso published asCA2062428A1, CA2062428C, CN1039086C, CN1064810A, DE69203488D1, DE69203488T2, DE69203488T3, EP0503521A1, EP0503521B1, EP0503521B2Publication number08216236, 216236, US 5382434 A, US 5382434A, US-A-5382434, US5382434 A, US5382434AInventorsPieter De Haan, M. DeurlooOriginal AssigneeAkzo N.V.Export CitationBiBTeX, EndNote, RefManPatent Citations (12), Non-Patent Citations (22), Referenced by (38), Classifications (22), Legal Events (7) External Links: USPTO, USPTO Assignment, EspacenetLow steroid dose dry pharmaceutical preparation
US 5382434 AAbstract
Disclosed are dry pharmaceutical preparations containing potent steroidal medicinal agents in combination with an excipient capable of binding the agent to an extent greater than 80% and a having a demixing potential of less than 10% for said agent. Such excipients include spray-dried polyalcohols, granulated α-lactose monohydrate, or mixtures thereof. Also disclosed is a process of manufacturing stable tablets containing nearly identical amounts of at least one steroidal medicinal agent present in each tablet in an amount varying from 0.005 to 0.5 percent by weight of the tablet. Also disclosed is a dry mix consisting essentially of 1 to 100 parts, by weight, of at least one medicinal agent uniformly distributed throughout 2000 to 20,000 parts, by weight, of the described excipients. The mixture can be used to make dry dosage forms such as capsules, tablets, powders, and slugged granulates.
1. A pharmaceutical dosage unit consisting essentially of 1 to 100 parts, by weight, of at least one steroidal medicinal agent uniformly distributed throughout 2000 to 20,000 parts, by weight, of an excipient capable of binding said steroidal medicinal agent to an extent greater than 80% and a demixing potential of less than 10% for said steroidal medicinal agent, in the form of tablets, capsules or slugged granulates.
This invention relates to pharmaceutical compositions generally, and more specifically to dry mixtures, tablets, pills or granulates containing potent steroid compounds.
Methods for making tablets and other solid or dry pharmaceutical preparations are well-known. For example in the well-known English language text Chase, et al, Remington's Pharmaceutical Sciences, pp. 1553-1576 (16th ed. 1980, Mack Publ. Co. of Easton, Pa., U.S.A.) ("Remington's"), methods of making tablets, capsules and pills and their respective components are described.
It has now been found that by dry mixing steroidal medicinal agents with excipients having a demixing potential of less than 10% and a binding affinity of greater than 80 percentage bound for these agents, a process results having surprisingly good properties with regard to robustness and ruggedness, while the resulting dry mixtures are very homogenous with regard to content uniformity even with very potent steroids.
FIGS. 1 to 4 show the relative distribution of a low dose component (0.05% EE w/w) among various sieve fractions of granulated α-lactose monohydrate, β-lactose, spray-dried lactose, and crystalline α-lactose monohydrate respectively.
The stable dry pharmaceutical preparation is preferably a tablet, capsule, pill, or powder. Tablets are the presently most preferred preparation.
Different types of the polyalcohol lactose were tested for their ability to be used with extremely low doses of steroids. Four different samples containing micronized EE (0.05% w/w) were made using:
Ten grams of ethinylestradiol and 50 grams of desogestrel are dry mixed with 19.440 kilograms of spray dried lactose (Pharmatose DCL 11). After mixing, 400 grams of sodium starch glycolate and 100 grams of magnesium stearate are incorporated into the mixture. The resulting mixture is then divided into halves, half of which is used to make 100 mg direct compression tablets, and the other half is used to make capsules. The tablets are tested for content uniformity as described in XXII, "<905> Uniformity of Dosage Units" at pages 1617-1619. The results show that the desogestrel and the EE are evenly distributed throughout the tablets. Similar tests on the capsules provide results showing even distribution of desogestrel throughout the powdered mixture.
SAMPLE 1. A dry mix sample containing only 0.05% by weight micronized ethinylestradiol ("EE"), obtained from Diosynth bv (Oss, NL), and the remainder spray dried lactose (Pharmatose DCL-11) was made by mixing the lactose with the EE for 2.5 mins.
The procedures of EXAMPLE III are repeated, except using 12.5 mg of digoxin and 9.875 grams (in total) spray-dried lactose. 100 tablets, each containing 125 μg of digoxin are made by direct compression of the dry mixture.
The binding affinity and demixing potential of various excipients vis-a-vis micronized ethinylestradiol were investigated. EE (0.05% w/w) was dry mixed with:
i) spray-crystallized dextrates (NF XVI) (Emdex™ Finnish Sugar Co., Ltd.),
Preliminary in vitro dissolution studies were conducted comparing the tablets of EXAMPLE I with desogestrel containing tablets such as those described in the third phase of Example VIII of EP-A-0 036 229 (corresponding to U.S. Pat. No. 4,378,356 to de Jager). The tablets were placed into an aqueous 0.1% sodium dodecyl sulfate solution, and the time required for the tablets to dissolve was measured.
The following tablets are made using a dry mix process according to the invention:
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Pharma, 5(3):152-159 (1989).3 *Cartillier and Moes, Influence dy Type de Lactose sur Cohesif et Faiblement Dose , S.T.P. Pharma, 5(3):152 159 (1989).4 *Chase et al., Remington s Pharmaceutical Sciences, pp. 1553 1576 (16th ed. 1980, Mack Publ. Co., Easton, Pa., USA.5Chase et al., Remington's Pharmaceutical Sciences, pp. 1553-1576 (16th ed. 1980, Mack Publ. Co., Easton, Pa., USA.6J. N. Staniforth, "Advances in excipient technology Powder and tableting characteristics," S.T. P. Pharma, vol. 6, No. 3, pp. 162-168, 1990.7J. N. Staniforth, "Advances in Powder Mixing and Segregation in Relation to Pharmaceutical Processing," Int. J. Pharm. & Prod. Mfr., vol. 3 (Suppl.) pp. 1-12, 1982, London, England.8 *J. N. Staniforth, Advances in excipient technology Powder and tableting characteristics, S.T. P. Pharma, vol. 6, No. 3, pp. 162 168, 1990.9 *J. N. Staniforth, Advances in Powder Mixing and Segregation in Relation to Pharmaceutical Processing, Int. J. Pharm. & Prod. Mfr., vol. 3 (Suppl.) pp. 1 12, 1982, London, England.10L. S. C. Wan et al., "Incorporation and Distribution of a low dose drug in granules" International Journal of Pharmaceutics, 88 (1992) pp. 159-163, no date.11 *L. S. C. Wan et al., Incorporation and Distribution of a low dose drug in granules International Journal of Pharmaceutics, 88 (1992) pp. 159 163, no date.12 *Martindale, The Extra Pharmacopoeia 28th edition; (1982); p. 54.13Nikolakakis & Newton, "Solid State Adsorption of Antibiotics onto Sorbiton" J. Pharm. Pharmacol., 41:145-148 (1989).14 *Nikolakakis & Newton, Solid State Adsorption of Antibiotics onto Sorbiton J. Pharm. Pharmacol., 41:145 148 (1989).15Schmidt & Benke, "Ubersattigte Geordnete Mischungen auf der Basis von Sorbit", Pharm. ind., 46(2):193-198 (1984).16 *Schmidt & Benke, Ubersattigte Geordnete Mischungen auf der Basis von Sorbit , Pharm. ind., 46(2):193 198 (1984).17Thiel and Nguyen, "Fluidized Bed Granulation of an Ordered Powder Mixture", J. Pharm. Pharmacol., 34:692-699 (1982).18 *Thiel and Nguyen, Fluidized Bed Granulation of an Ordered Powder Mixture , J. Pharm. Pharmacol., 34:692 699 (1982).19Thiel et al. "Fluidised Bed Granulation of an Ordered Powder Mixture Reduces the Potential for Ordered Unit Segregation", Powder Technology, 34:75-80 (1983).20 *Thiel et al. Fluidised Bed Granulation of an Ordered Powder Mixture Reduces the Potential for Ordered Unit Segregation , Powder Technology, 34:75 80 (1983).21Thiel et al., "Content Uniformity of microdose Tablets (dosage lug-10 mg) Produced by Fluid Bed Granulation of Interactive Mixtures", J. Pharmacol., 38:335-343 (1986).22 *Thiel et al., Content Uniformity of microdose Tablets (dosage lug 10 mg) Produced by Fluid Bed Granulation of Interactive Mixtures , J. Pharmacol., 38:335 343 (1986).* Cited by examinerReferenced byCiting PatentFiling datePublication dateApplicantTitleUS6077533 *Jan 12, 1998Jun 20, 2000Purdue Pharma L.P.Powder-layered oral dosage formsUS6187339 *Oct 17, 1995Feb 13, 2001Akzo Nobel N.V.Solid pharmaceutical composition comprising an excipient capable of binding waterUS6343602Apr 13, 2000Feb 5, 2002Gsf Forshungszentrum Fur Umwelt Und GesMethod of and a device for dry application of substances on inhalable pulverulent carrier substancesUS6962908Dec 21, 2001Nov 8, 2005Warner Chilcott Company Inc.Oral pharmaceutical products containing 17 β-estradiol-3-lower alkanoate, method of administering the same and process of preparationUS7118765Oct 18, 2002Oct 10, 2006Spi Pharma, Inc.Co-processed carbohydrate system as a quick-dissolve matrix for solid dosage formsUS7399528 *Mar 23, 2004Jul 15, 2008Chiesi Farmaceutici S.P.A.Powder particles with smooth surface for use in inhalation therapyUS7572779Apr 29, 2004Aug 11, 2009Warner Chilcott Company LlcOral pharmaceutical products containing 17β-estradiol-3-lower alkanoate, method of administering the same and process of preparationUS7732431 *Sep 18, 2006Jun 8, 2010Aventis Pharma SaPharmaceutical compositions comprising trimegestoneUS7799771Sep 21, 2010Warner Chilcott Company, Llc.Oral pharmaceutical products containing 17β-estradiol-3-lower alkanoate, method of administering the same and process of preparationUS7867990Jan 11, 2011Ortho-Mcneil Pharmaceutical, Inc.Steroid hormone products and methods for preparing themUS8288342Oct 16, 2012Teva Women's Health, Inc.Methods for treating vasomotor symptoms in castrated prostatic cancer patients with low dose cyproterone acetateUS8501236Feb 29, 2012Aug 6, 2013Campina B.V.Method for producing a crystalline tableting additive, additive thus obtained and use thereofUS8545889Jun 6, 2006Oct 1, 2013Spi Pharma, Inc.Co-processed carbohydrate system as a quick-dissolve matrix for solid dosage formsUS8617588Mar 9, 2010Dec 31, 2013Spi Pharma, Inc.Highly compactable and durable direct compression excipients and excipient systemsUS9012667 *Feb 8, 2011Apr 21, 2015Laboratoire TheramexProcess for introducing a double bond into position 15, 16 of a steroidUS9138413Sep 27, 2013Sep 22, 2015Spi Pharma, Inc.Co-processed carbohydrate system as a quick-dissolve matrix for solid dosage formsUS9358212Dec 5, 2013Jun 7, 2016Spi Pharma, Inc.Highly compactable and durable direct compression excipients and excipient systemsUS20020132801 *Jan 11, 2001Sep 19, 2002Schering AktiengesellschaftDrospirenone for hormone replacement therapyUS20030114429 *Feb 6, 2003Jun 19, 2003Schering AktiengesellschaftPharmaceutical composition for use as a contraceptiveUS20030118642 *Oct 18, 2002Jun 26, 2003Norman Gary TelferCo-processed carbohydrate system as a quick-dissolve matrix for solid dosage formsUS20030119798 *Feb 6, 2003Jun 26, 2003Schering AktiengesellschaftPharmaceutical composition for use as a contraceptiveUS20040014714 *Jul 19, 2001Jan 22, 2004Kussendrager Klaas DanielMethod for producing a crystalline tableting additive, additive thus obtained and use thereofUS20040209856 *Apr 29, 2004Oct 21, 2004Galen (Chemicals) LimitedOral pharmaceutical products containing 17beta-estradiol-3-lower alkanoate, method of administering the same and process of preparationUS20050118113 *Mar 23, 2004Jun 2, 2005Chiesi Farmaceutici S.P.A.Powder particles with smooth surface for use in inhalation therapyUS20050234028 *Jun 17, 2005Oct 20, 2005Warner Chilcott Company Inc.Oral pharmaceutical products containing 17beta-estradiol-3-lower alkanoate, method of administering the same and process of preparationUS20060016830 *Jun 9, 2005Jan 26, 2006Smithkline Beecham CorporationApparatus and method for pharmaceutical productionUS20060058272 *Nov 4, 2005Mar 16, 2006Juergen HilmanPharmaceutical composition for use as a contraceptiveUS20070219169 *Sep 18, 2006Sep 20, 2007Sanofi-AventisPharmaceutical compositions comprising trimegestoneUS20100226964 *Mar 9, 2010Sep 9, 2010Spi Pharma, Inc.Highly Compactable and durable direct compression excipients and excipient systemsUS20100260860 *Oct 14, 2010Ahmed Salah UMethods for Treating Vasomotor Symptoms in Castrated Prostatic Cancer Patients with Low Dose Cyproterone AcetateUS20110046095 *Nov 2, 2010Feb 24, 2011Thomas SchultzSteroid hormone products and methods for preparing themUS20110046099 *Feb 24, 2011Thomas SchultzSteroid hormone products and methods for preparing themUS20130137885 *Feb 8, 2011May 30, 2013Laboratoire TheramexProcess for introducing a double bond into position 15, 16 of a steroidUS20140309204 *Jun 26, 2014Oct 16, 2014Janssen Pharmaceuticals, Inc.Steroid hormone products and methods for preparing themDE19917347A1 *Apr 16, 1999Nov 9, 2000Gsf Forschungszentrum UmweltVerfahren und Vorrichtung zum trockenen Anbringen von Substanzen an inhalierbare pulverf�rmige Tr�gerstoffeEP2178540A1 *Jul 30, 2008Apr 28, 2010Stellan Hjert�nPharmaceutical composition suitable for adsorption to the cell surface of pathogenic microbesWO1997026798A1 *Jan 25, 1995Jul 31, 1997Wm. Wrigley Jr. CompanyImproved rolling compound and methods of manufacturing chewing gum using sameWO2012120365A1Mar 6, 2012Sep 13, 2012Aurobindo Pharma LimitedStable pharmaceutical composition comprising ethinyl estradiol* Cited by examinerClassifications U.S. Classification424/465, 514/960, 514/175, 424/464, 514/171, 514/169, 514/174International ClassificationA61K9/14, A61K31/57, A61K9/16, A61K47/10, A61K47/26, A61K31/56, A61K9/20, A61K31/565Cooperative ClassificationY10S514/96, A61K31/57, A61K31/565, A61K9/2018European ClassificationA61K31/57, A61K9/20H4B, A61K31/565Legal EventsDateCodeEventDescriptionJul 9, 1998FPAYFee paymentYear of fee payment: 4Jun 24, 2002FPAYFee paymentYear of fee payment: 8Jul 6, 2006FPAYFee paymentYear of fee payment: 12Jan 30, 2007ASAssignmentOwner name: N.V. ORGANON, NETHERLANDSFree format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:AKZO NOBEL N.V.;REEL/FRAME:018816/0737Effective date: 20070112Owner name: N.V. 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Patent US20080203322 - Resist collapse prevention using immersed hardening - Google PatentsSearch Images Maps Play YouTube News Gmail Drive More »Sign in<nobr>Advanced Patent Search</nobr>PatentsA method, tool, and machine for hardening a photoresist image while the photoresist image is immersed in a liquid....http://www.google.com/patents/US20080203322?utm_source=gb-gplus-sharePatent US20080203322 - Resist collapse prevention using immersed hardeningAdvanced Patent SearchPublication numberUS20080203322 A1Publication typeApplicationApplication numberUS 12/150,955Publication dateAug 28, 2008Filing dateMay 1, 2008Priority dateJan 25, 2005Also published asUS7384726, US7767984, US20060166143Publication number12150955, 150955, US 2008/0203322 A1, US 2008/203322 A1, US 20080203322 A1, US 20080203322A1, US 2008203322 A1, US 2008203322A1, US-A1-20080203322, US-A1-2008203322, US2008/0203322A1, US2008/203322A1, US20080203322 A1, US20080203322A1, US2008203322 A1, US2008203322A1InventorsBurn-Jeng Lin, Ching-Yu ChangOriginal AssigneeTaiwan Semiconductor Manufacturing Co., Ltd.Export CitationBiBTeX, EndNote, RefManClassifications (6), Legal Events (1) External Links: USPTO, USPTO Assignment, EspacenetResist collapse prevention using immersed hardeningUS 20080203322 A1Abstract A method, tool, and machine for hardening a photoresist image while the photoresist image is immersed in a liquid.
25. A tool for making a semiconductor device comprising:
a means for hardening a photoresist image while the photoresist image is immersed in a liquid. 26. A tool as set forth in claim 25 further comprising a means for pressurizing the liquid.
27. A tool as set forth in claim 26 further comprising a heating means for the liquid.
28. A tool as set forth in claim 26 further comprising a heating means for the liquid.
29. A tool as set forth in claim 25 further comprising an ultraviolet illuminator.
30. A tool as set forth in claim 29 wherein the ultraviolet illuminator comprises at least an ultraviolet light source and an ultraviolet condenser.
31. A tool as set forth in claim 29 wherein the ultraviolet illuminator produces wavelengths between 150 nm and 480 nm.
32. A tool as set forth in claim 25 comprising an infrared illuminator.
33. A tool as set forth in claim 32 wherein the infrared illuminator comprises an infrared source and an infrared condenser.
34. A tool as set forth in claim 32 wherein the infrared illuminator produces infrared light comprising wavelengths between 700 nm and 2 microns.
35. A semiconductor manufacturing machine comprising:
a photoresist deposing station, a photoresist exposure station, a post exposure bake station, a developing station, a rinse station, a photoresist hardening station and a drying station. 36. A semiconductor manufacturing machine as set forth in claim 35 wherein the hardening station comprises an ultraviolet light source.
37. A semiconductor manufacturing machine as set forth in claim 35 wherein the hardening station comprises an infrared source.
38. A semiconductor manufacturing machine as set forth in claim 35 wherein the hardening station comprises a heated for heating a liquid.
39. A semiconductor manufacturing machine as set forth in claim 35 wherein the photoresist exposure station comprises an ArF source. Description
This application is a Divisional of U.S. patent application Ser. No. 11/043,598 filed Jan. 25. 2005.
FIELD OF THE INVENTION This invention relates to methods of making semiconductor devices, and more particularly, to a method of making a semiconductor device including forming a photoresist features and treating the same to prevent the photoresist features from collapsing
BACKGROUND OF THE INVENTION FIG. 1 illustrates a prior art method of making a semiconductor device including providing a semiconductor device 10 with a first layer 6 such as a dielectric layer having an upper surface 8. A photoresist layer 26 is deposited over the upper surface 8 of the first layer 6 and patterned and a development composition 22 is flowed over the photoresist layer 26 so that individual photoresist features are defined, such as a first photoresist feature 12 and a second photoresist feature 14 with a gap 16 therebetween. The first photoresist feature 12 includes an inside wall 18 facing an inside wall 20 of the second photoresist feature 14. The photoresist features 12 and 14 have an outside wall 19 and 21 respectively. FIG. 2 illustrates a prior art step in the semiconductor manufacturing wherein the development fluid or rinse fluid is spun dry in an effort to leave the individual photoresist features 12, 14. However, the photoresist features 12, 14 can collapse as illustrated in FIG. 2. The collapsing becomes more prevalent in situations where the aspect ratio, that is the photoresist thickness (height)/photoresist width ratio is greater than 3. The collapse problem is also prevalent when small photoresist features such as line widths less than 150 nm are formed.
As will be appreciated from FIG. 2, when the photoresist collapses typically the inner side wall 18 of the first photoresist feature 12 engages the inner side wall 20 of the second photoresist feature 14 to close off the gap 16 that was therebetween. FIG. 4 is a plan illustration of the collapsed photoresist features 12 and 14. It will be appreciated that there is no opening or gap 16 between the first photoresist feature 12 and the second photoresist feature 14 and therefore wet or dry etching materials, or other material cannot pass between the photoresist features.
Messick et al., U.S. Pat. No. 6,451,510, discloses one solution to preventing photoresist collapse. Messick et al. discloses a method of developing photoresist patterns on electronic component substrates such as semiconductor wafers using specially defined developer compositions in sequence with a specially defined rinse composition to develop an exposed photoresist pattern and then the developed pattern is rinsed. Both the developer composition and the rinse composition contain an anionic surfactant and, when these solutions are used in sequence, they form a photoresist pattern which avoids pattern collapse even with small features such as line widths less than 150 nm and with aspect ratios greater than about 3. Disclosed as suitable anionic surfactants are ammonium perfluoroalkyl sulfonate and ammonium perfluoroalkyl carboxylate.
SUMMARY OF THE INVENTION One embodiment of the invention includes a method of making a semiconductor device including immersing a photoresist image in a liquid and hardening the photoresist image while immersed in the liquid.
In one embodiment of the invention the hardening of the photoresist image comprises directing infrared light on a photoresist image.
In another embodiment of the invention the hardening of the photoresist image comprises directing infrared radiation comprising wavelengths ranging from 700 nm to 2 micrometers.
One embodiment of the invention further comprises heating the liquid prior to immersing the photoresist image therein.
One embodiment of the invention further comprises pressurizing the liquid to raise its boiling point.
In another embodiment of the invention the liquid comprises a reactive substance to react with the photoresist.
In one embodiment of the invention the hardening comprises electrically heating of the liquid.
In another embodiment of the invention the liquid comprises water and further comprising electrically heating the water.
In another embodiment of the invention the hardening comprises directing ultraviolet light on the photoresist image.
In another embodiment of the invention comprises directing ultraviolet light on the photoresist image and heating the liquid.
Another embodiment of the invention comprises directing ultraviolet light on the photoresist image and wherein the ultraviolet light includes wavelengths between 150 nm and 480 nm.
In another embodiment of the invention the liquid comprises a surfactant.
In another embodiment of the invention the surfactant comprises an alcohol.
In another embodiment of the invention the photoresist comprises a material including at least one of OH− or COO− functional groups and wherein the liquid comprises a chemical that reacts with at least of one said functional groups.
Another embodiment of the invention comprises a tool for hardening a photoresist image while the photoresist image is immersed in a liquid.
Another embodiment of the invention further includes a pressurizing means for the liquid.
Another embodiment of the invention includes a heating means for the liquid.
Another embodiment of the invention includes an ultraviolet illuminator.
Another embodiment of the invention includes an ultraviolet illuminator comprising at least one ultraviolet source and at least one ultraviolet condenser.
Another embodiment of the invention includes an ultraviolet light source capable of producing wavelengths between 150 nm and 480 nm.
Another embodiment of the invention comprises an infrared illuminator.
Another embodiment of the invention comprises an infrared illuminator comprising at least one infrared source and at least one infrared condenser.
Another embodiment of the invention includes an infrared light source capable of producing wavelengths between 700 nm and 2 micrometers.
Another embodiment of the invention includes a chamber and means for flowing a liquid into the chamber.
Another embodiment of the invention includes a semiconductor wafer assembly machine comprising a photoresist depositing station, an exposure station, a PEB station, a developing station, a rinse station, a photoresist hardening station, and a drying station.
BRIEF DESCRIPTION OF THE DRAWINGS Embodiments of the present invention will become more fully understood from the detailed description and the accompanying drawings, wherein:
FIG. 1 illustrates a prior art method of developing a photoresist image.
FIG. 2 illustrates a prior art method wherein photoresist features collapse during spin drying.
FIG. 3 illustrates the capillary force in the fluid between photoresist elements.
FIG. 4 illustrates a plan view of a prior art semiconductor with photoresist elements collapsed.
FIG. 5A illustrates a method according to one embodiment of the present invention including forming a photoresist layer over a substrate.
FIG. 5B illustrates a method according to one embodiment of the present invention including exposing the photoresist layer.
FIG. 5C illustrates a method according to one embodiment of the present invention including a PEB step.
FIG. 5D illustrates a method according to one embodiment of the present invention including immersing a photoresist layer in a developer composition.
FIG. 5E illustrates a method according to one embodiment of the present invention including rinsing the photoresist layer.
FIG. 5F illustrates a method according to one embodiment of the present invention including directing ultraviolet light onto the photoresist image while the image is immersed in a fluid to harden the photoresist image.
FIG. 5G illustrates a method according to one embodiment of the present invention including spin drying the semiconductor device after the photoresist image has been hardened and so that the photoresist image features do not collapse.
FIG. 6 illustrates an alternative embodiment of the present invention including heating a liquid in which a photoresist image is immersed to harden the photoresist image.
FIG. 7 illustrates a semiconductor manufacturing tool according to one embodiment of the present invention.
FIG. 8 illustrates a semiconductor assembly machine according to one embodiment of the present invention including a variety of stations.
FIG. 9 illustrates a plan view of a semiconductor wafer according to one embodiment of the present invention including photoresist image that has been hardened while immersed in a fluid according to the present invention.
Referring now to FIG. 3, as indicated earlier, a semiconductor device 10 may include a first photoresist feature 12 and a second photoresist feature 14 with a gap 16 therebetween. The first photoresist element 12 includes an inner wall 18 which is hydrophilic. The second photoresist element 14 includes an inner wall 20 which is also hydrophilic. One aspect of the present invention includes the discovery that the adjacent photoresist elements 12 and 14 create a capillary force in the fluid 22 that is therebetween.
Referring now to FIGS. 5A-G, one embodiment of the present invention includes making a semiconductor device including depositing a photoresist layer 26 over a first layer 24, which may be a substrate, dielectric layer, or metallization layer as shown in FIG. 5A. As shown in FIG. 5B, the photoresist layer 26 is exposed to light 28 shown through a mask 31 including blocking portions 33 that do not allow light to pass therethrough. The photoresist layer 26 includes exposed portions 25 and unexposed portions 27. As shown in FIG. 5C, the photoresist layer 26 is then subjected to a post exposure bake (PEB) step.
Thereafter, the photoresist layer 26 is exposed to a developer composition 32 which dissolves the exposed portion 25 of the photoresist layer 26 as shown in FIG. 5D. Referring now to FIG. 5E, the semiconductor device is rinsed so that the remaining unexposed portions 27 of the photoresist layer 26 are immersed in the rinse solution 34. As shown in FIG. 5F, thereafter the photoresist image is hardened, for example, by exposing the remaining elements 27 to ultraviolet light 106 while the photoresist elements 27 are immersed in a liquid 34. As shown in FIG. 5G, the semiconductor device 10 is then dried, for example, by spin drying to remove the rinse liquid and so that the photoresist elements 12 and 14 do not collapse and a gap 16 remains therebetween.
Referring now to FIG. 6, an alternative embodiment of the present invention includes heating the liquid 34 in which the photoresist elements 27 are immersed. The heating of the liquid 34 may occur prior to immersing the photoresist elements 27 in the liquid 34 or after the photoresist elements 27 have been immersed in the liquid 34, for example, by using a heater 108. The heating of the liquid may be accomplished by electrical heating, liquid gas heat exchanger or any other method known to those skilled in the art of heating a liquid. The liquid may be placed under pressure by, for example, by charging a gas through a port 110 into the chamber 42.
Referring now to FIG. 7, one embodiment of the invention includes a tool for hardening a photoresist image while immersed in the liquid. The tool 40 may include a chamber 42 and a support 44 for a semiconductor wafer. The tool may include an illuminator 46 which may be, for example, an ultraviolet light illuminator or an infrared radiation illuminator. The tool may also include a means for heating 38 a fluid introduced into the chamber, for example, through a port 100. The tool 40 may also include a means for applying pressure to the fluid, for example by, charging gas through a gas port 48.
Referring now to FIG. 8, one embodiment of the invention includes a semiconductor machine including a photoresist depositing station 50, an exposure station 52 for exposing the photoresist material deposited on the semiconductor wafer, a PEB station 54, a developing station 56, a rinsing station 58, a photoresist hardening station 60 and a drying station 70.
In conventional processing, dense photoresist patterns suffer from collapse. To prevent such collapse, prior methods kept the photoresist thickness/width ratio to less than 3. However, conventional etching process often require this ratio to be greater than 3. The problem was even worse for ArK photoresist because ArF photoresist are less etch resistant. Furthermore, design features for ArF photoresist are smaller than KrF photoresist. The hardening method of the present invention overcomes these prior art problems and the method can be used to make photoresist features in dense design dimensions and using a variety of exposure sources without the photoresist collapsing during the drying step. The photoresist features hardened according to the present invention allow for the trimming of the photoresist features to reduce the width of the feature. The photoresist features may be trimmer using a laser after the drying step.
Classifications U.S. Classification250/492.2International ClassificationG21G5/00Cooperative ClassificationG03F7/2024, G03F7/40European ClassificationG03F7/40, G03F7/20B2Legal EventsDateCodeEventDescriptionJan 8, 2014FPAYFee paymentYear of fee payment: 4RotateOriginal ImageGoogle Home - Sitemap - USPTO Bulk Downloads - Privacy Policy - Terms of Service - About Google Patents - Send FeedbackData provided by IFI CLAIMS Patent Services©2012 Google


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THE 10 BEST Sights & Historical Landmarks in Downpatrick - TripAdvisor
Things to do near Dunleath House B&B
Top Sights in Downpatrick, Northern Ireland
Downpatrick Landmarks
More weather for Downpatrick
We found great results, but some are outside Downpatrick. Showing results in neighboring cities.
#2 of 10 Sights & Landmarks in Downpatrick
“The walks and views are breathtaking a real hidden gem You can also visit the big Victorian house but the setting is spectacular it's an outside attraction close to the beautiful village of strangeford where you c...”
#3 of 10 Sights & Landmarks in Downpatrick
“We were actually too late to see the inside of the cathedral because it was closed, but were pleased to see St. Patrick's burial site right inside the cemetery.”
“The stones are set in a circle with beautiful views all around and the hawthorn tree/bush amongst them, that people have left gifts on and around.”
“Took the dog out for a run on day ended up in Saul so I walked buster up to the saint Patrick's statue what a lovely view you could see for miles at night the statue is light up in green you can see it light up fo...”
“I’ve climbed the hill many times and always been rewarded by the spectacular views which showcase the County Down countryside.”
#6 of 10 Sights & Landmarks in Downpatrick
“When in Downpatrick, try to visit Saul church, the site of St Patrick's first church in Ireland (probably!).”
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“Despite the rather damp day and mud underfoot it was a pleasure to visit this very interesting site.”
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#9 of 10 Sights & Landmarks in Downpatrick
Dundrum Castle Newcastle 7.0 mi away
#10 of 10 Sights & Landmarks in Downpatrick


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Keeping International Commitments: Compliance, Credibility and the G7, 1988-1995 by Eleonore Kokotsis | 9780815333326 | Hardcover | Barnes & Noble® B&N's Biggest Books Book Awards Book Graph Books by Author Books by Series Collectible Editions Coming Soon Coupons & Deals Discover Categories New Releases NY Times Bestsellers The Paperback Store Signed Books
by Eleonore KokotsisEleonore Kokotsis
0815333323
9780815333326
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This study is the first to offer explanations for compliance with G7 commitments by identifying the patterns, explaining the causes and exploring the processes of this compliance from 1988-1995. It provides the only systematic review of the G7's compliance record in the post-Cold War globalizing system of the 1990s and in regard to important environment and development commitments that have often dominated the Summit's agenda during this third cycle of summitry. It draws on explanatory factors for Summit compliance from three bodies of international relations theory-including regime theory, concert theory and the recent extension of regime theory to embrace the effects of domestic political institutions.
Begins the task of identifying the patterns, explaining the causes, and exploring the processes of compliance with environmental and development commitments made by the richest countries in the world during the decade after the Cold War. Draws on explanatory factors from three bodies of international relations theory<-->regime, concert, and institutional theory<-->to provide a synthetic explanation of compliance. Also traces the process by which commitments are translated into national policy adjustment, by examining how the obligations affect and are affected by salient institutions and actors within a national government's policy-making process. Seems to have been a doctoral dissertation for the University of Toronto. US distribution is by Taylor and Francis. Annotation c. Book News, Inc., Portland, OR (booknews.com)

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Cardinals Winter Ball Stat Lines – 01/07 - St. Louis - Scout
Cardinals Winter Ball Stat Lines – 01/07Josh Jones01/08/2008Looking at the numbers put up by St. Louis Cardinals prospects in winter ball action on Monday, January 7. Amaury Marti was named Player of the Week in Nicaragua.Venezuelan League<?xml:namespace prefix = o ns = "urn:schemas-microsoft-com:office:office" />
Rico <?xml:namespace prefix = st1 ns = "urn:schemas-microsoft-com:office:smarttags" />Washington (Springfield) 1-for-4 with 1 run, 1 strike out, assisted in 1 double play and had 1 fielding error.
Caribes lost 4-3: link
Juan Richardson (Springfield-free agent) 0-for-1 with 1 strike out.
Gigantes lost 3-2: link
Amaury Marti (Springfield) was named Player of the Week for the Jan. 1-7 time period. Marti went 5-for-8 with a .625 AVG, 1 double, 2 home runs, 4 runs, and 5 RBI's in 2 games. link
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