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Patent US5827613 - Articles having diamond-like protective film and method of manufacturing the ... - Google PatentsSearch Images Maps Play YouTube News Gmail Drive More »Sign inPatentsArticles having a diamond-like protective film formed thereon, each comprising a substrate of a material selected from the group consisting of alloys containing at least Co, Ni, or Fe, ceramics, and glass and which has only a slight affinity for a diamond-like thin film, an Mo film formed on the substrate,...http://www.google.com/patents/US5827613?utm_source=gb-gplus-sharePatent US5827613 - Articles having diamond-like protective film and method of manufacturing the sameAdvanced Patent SearchTry the new Google Patents, with machine-classified Google Scholar results, and Japanese and South Korean patents.Publication numberUS5827613 APublication typeGrantApplication numberUS 08/209,571Publication dateOct 27, 1998Filing dateMar 10, 1994Priority dateSep 4, 1992Fee statusLapsedPublication number08209571, 209571, US 5827613 A, US 5827613A, US-A-5827613, US5827613 A, US5827613AInventorsMasatoshi Nakayama, Masanori ShibaharaOriginal AssigneeTdk CorporationExport CitationBiBTeX, EndNote, RefManPatent Citations (13), Non-Patent Citations (3), Referenced by (32), Classifications (24), Legal Events (6) External Links: USPTO, USPTO Assignment, EspacenetArticles having diamond-like protective film and method of manufacturing the same
US 5827613 AAbstract
Articles having a diamond-like protective film formed thereon, each comprising a substrate of a material selected from the group consisting of alloys containing at least Co, Ni, or Fe, ceramics, and glass and which has only a slight affinity for a diamond-like thin film, an Mo film formed on the substrate, and a diamond-like thin film formed further thereon. Such articles are manufactured by a method which comprises holding a grid made of Mo close to the surface of the substrate, bombarding the grid and the substrate surface with a bombarding gas consisting of inert gas atoms of Ar or the like, thereby removing contaminants from the surface and depositing Mo atoms on the substrate surface to form an Mo film thereon, ionizing a low-molecular-weight hydrocarbon or a feed gas capable of producing a low-molecular-weight hydrocarbon upon decomposition or reaction, and then accelerating the resulting ions and depositing the same on the Mo film to form a diamond-like film thereon. The substrate is preferably a metallic mold constructed of a hardened steel. The Mo film enhances the bond of the diamond-like film to the substrate and improves the strength of the mold surface.
1. An article having a diamond-like film formed thereon which comprises a substrate of a material selected from the group consisting of alloys containing at least Co, Ni, or Fe, ceramics, and glass and which has only a slight affinity for a diamond-like thin film, an Mo film formed on the substrate, and a diamond-like thin film consisting of an amorphous carbon having a Raman's absorption at about 1,550 cm-1 but not having a sharp peak at 1,333 cm-1 formed further thereon with the substrate at no greater than 520° C. and said diamond-like thin film having a thickness of 0.1-100 μm.
2. The article of claim 1 in which said diamond-like thin film has been formed with the substrate at no greater than 520° C.
4. The article of claim 1, wherein the Mo film consists essentially of Mo.
This application is a continuation-in-part application of application Ser. No. 07/940,593, filed Sep. 4, 1992 and now abandoned.
This invention relates to articles protected with diamond-like thin film, such as metallic molds, and a method of manufacturing the articles. More particularly, it relates to a film-forming technology whereby the adhesion or bond properties of a diamond-like thin film are improved with respect to certain substrates, such as metallic molds, to which the films usually are slightly adhesive or binding.
"Diamond-like film" or "diamond-like thin film" used herein in connection with the present invention is defined as an amorphous carbon film having a Raman's absorption at about 1,550 cm-1. It should be noted that the diamond-like film is clearly different from diamond film because the latter has a sharp Raman's absorption peak at 1,333 cm-1 and is an aggregate of micro crystals. Diamond-like film does not have Raman's absorption peak at 1,333 cm-1 and usually such diamond-like film or diamond-like thin film has a Vickers hardness Hv of at least 5,000 kg/mm2 (refer, e.g., to TRC News, January 1987, Vol. 6-1, page 7, published by Torey Research Center and Journal of Applied Physics of Japan, Vol. 55, No. 7 (1986), page 640).
The diamond-like thin film produced by a vapor phase process has great hardness and outstanding wear resistance, durability, and resistance to chemical and corrosive attacks. Also it can form coatings on articles of whatever shapes desired. It is therefore useful or promising as protective coatings for articles that require one or more such beneficial properties, e.g., injection, extrusion, and compression molds and dies for glass and plastics.
Methods of manufacturing diamond-like thin films by the vapor phase process are varied (refer, e.g., to HYOMEN KAGAKU (Surface Chemistry), vol. 5, No. 108 (1984), pp. 108-115 "Various methods"). Diamond-like thin films are extensively used as corrosion-resistant and wear-resistant protective films coating the surfaces of variously shaped articles that need to be protected.
The diamond-like thin films thus produced by prior art techniques, however, have had a common problem of easily coming off from the substrate surfaces upon subjection to external forces. This is attributable, for one thing, to their weak forces of binding to certain types of substrates and, for the other, to the high surface coarseness of the diamond-like thin films which themselves are aggregates of microcrystals. The shortcoming makes the films unable to be fully effective as protective coatings for applications where corrosion resistance or wear resistance is of essential importance. In particular, Fe metals and alloys (e.g., soft steel "STC", stainless steel, and hardened steels "SKD", "SKS"), alloys of other metals such as Co and Ni, glass, and ceramics are known to produce weak bonds between themselves and diamond-like thin films. Iron-based substrates are in use, e.g., for metallic molds and sliding parts, or the applications of the highest industrial utility. Glass and ceramics too have a broad range of applications including sliding members of thermal heads. It is therefore important to improve the adhesiveness of diamond-like thin films to the substrate surfaces on which they are formed.
The molds or dies for injection molding, extrusion, compression molding, etc. of glass and plastics have hitherto been made from cemented carbides. The materials are expensive and require much time and cost to procure and fabricate into the objects. Susceptibility to cracking due to the lack of toughness is another disadvantage. The brittleness of the cemented carbides has to be compensated for and their abrasion resistance be enhanced. To this end, it has been proposed to coat the frictional or sliding surfaces of metallic molds protectively with diamond-like thin films, e.g., by Japanese Patent Application Nos. 60285/1988 and 170849/1988. However, those thin films do not bind firmly enough to the metallic mold substrate surfaces. The inadequate binding force combines with the high surface roughness on account of the aggregation of microcrystals to make the films easy to separate from the mold substrate surfaces by dint of external forces. With the substrate materials of the character, therefore, the diamond-like films have not proved fully satisfactory as protective coatings.
Hardened steels, on the other hand, are available at lower cost and do not squander much time and cost for fabrication but the formed surfaces of metallic mold substrates are worn faster and hence have shorter life. The drawback could be overcome by coating the surfaces with a diamond-like thin film formed by a vapor phase process, as proposed by the above-mentioned two Japanese Patent Applications. However, by the same token, the binding force is insufficient. There are other approaches to the manufacture of diamond-like thin films (refer, e.g., to HYOMEN KAGAKU (Surface Chemistry), vol. 5, No. 108 (1984), pp. 108-115 "Various methods"). Those methods require substrate temperatures high as 600° C. or upwards, which can anneal the hardened steels and impair the hardness of the resulting molds.
Pretreatment of such substrates has been taught, e.g. , by Japanese Patent Application Public Disclosure Nos. 200898/1985, 204695/1985, and 174376/1986. No. 200898/1985 recommends ion etching of a Co-WC alloy substrate surface by direct action of DC or AC glow discharge before a diamond-like thin film is formed on the surface as a high-hardness film. The ion etching is aimed at increasing the film-forming rate through an increase in the number of nuclei for the growth of diamond crystals. Since no accelerating voltage is applied, the etching efficiency is not adequately high from the standpoint of enhanced adhesion. The improvement in adhesion to which the present invention is directed is not satisfactorily achieved. No. 204695/1985 likewise aims at an increase in the film-forming rate. The end is attained by introducing Ar gas into a reduced-pressure chamber, applying a voltage across positive and negative electrodes to produce a plasma, and then subjecting a substrate to the plasma action. The plasma ion concentration being limited, the etching effect is rather too low for the improvement of adhesion. No. 174376/1986 improves the adhesion of substrates by treatment with plasma gas and then by oxidation treatment to form an oxide coating. The process uses high frequency waves for the production of a plasma and accelerates positive ions in the plasma that have passed through a grid at positive potential toward a metallic substrate connected to a negative potential. Consequently, the plasma requires diffusion in the first place so that the positive ions can pass through the positive-potential grid. This makes it impossible for a sufficient amount of positive ions to form a film to reach the substrate, with the result that the adhesion cannot be improved to a satisfactory level. In order to overcome these difficulties of the prior art, we previously proposed, in patent application Ser. No. 214913/1989, pretreatment of a substrate by bombardment with high-energy Ar ions or the like. Still the treatment did not bring an adequately enhanced adhesion.
In a further effort to correct the foregoing disadvantages and achieve a real improvement in adhesion, Patent Application Public Disclosure No. 62468/1989 proposed the interposition of an intermediate layer. The layers used for this purpose include those of metals, such as, silicon, aluminum, tungsten, cobalt, and nickel; metal carbides, such as silicon carbide and tungsten carbide; metal nitrides, such as silicon nitride, tungsten nitride, and titanium nitride; and metal oxides, such as silica, alumina, and zirconia.
These intermediate layers, which have to be formed by vacuum deposition or chemical vapor deposition (CVD), complicate the process and require an equipment in addition to the apparatus for forming a diamond-like film. Moreover, the properties of the resulting intermediate layers are not fully acceptable yet.
None of these printed publications of the prior art suggest that the use of an Mo-intermediate layer makes it possible to form an excellently adherent and hard diamond-like film on a bulk metal such as stainless steel or steel containing Fe, Co, etc.
The present invention has for its object to provide articles, such as metallic molds, protected with a diamond-like thin film which is strongly bound to and highly adhesive to the substrate and exhibits improved peeling resistance and durability, and provide also a method of manufacturing such articles.
The invention provides a method of forming a diamond-like film on articles, which comprises disposing a grid made of Mo close to a substrate which is made of a material selected from the group consisting of alloys containing at least one chosen from among Co, Ni, and Fe, ceramics, and glass and which has only a slight affinity for the diamond-like thin film, causing a bombarding gas of the atoms of an inert gas such as Ar to bombard both the substrate surface and the grid to remove contaminants from the substrate surface and allow the grid to release Mo atoms onto the substrate to form an Mo film thereon, ionizing a low-molecular-weight hydrocarbon or a feed gas capable of giving a low-molecular-weight hydrocarbon upon decomposition or reaction and thereby producing ions, and then accelerating the ions for deposition on the Mo film, whereby a diamond-like film is formed thereon. The invention provides also articles having a diamond-like protective film thus formed. The articles to which the invention is directed more specifically are metallic molds based on substrates of hardened steel.
FIG. 1 is a vertical sectional view of an apparatus for forming an Mo-diamond-like protective film in accordance with the present invention;
FIG. 2 is a vertical sectional view of another apparatus for producing an Mo-diamond-like protective film embodying the invention; and
FIG. 3 is a fragmentary, perspective view of a filament unit in an apparatus for producing an Mo-diamond-like protective film according to the invention.
According to this invention, the formation of an Mo film on the substrate is accomplished, simultaneously with the effect of Ar bombardment of the substrate in conformity with our copending patent application Ser. No. 214913/1989. Both solid bonding of Mo to the substrate and strong bonding of the diamond-like protective film to the Mo-intermediate layer are thus realized. The improved bonding and adhesion to the substrate permits the use of the resulting articles for applications where their wear resistance is evaluated under stringent conditions. Under the invention the Mo film forming and the diamond-like film forming are performed, one after another, by the same apparatus. This simplifies the process and reduces the cost.
The present invention is based on the fact that the formation of a diamond-like film by ionization evaporation is effected by an apparatus which comprises thermionic ionizing means and an electric field-applying grid for accelerating the ions of an ionized hydrocarbon. The end of the invention is achieved by using a grid of Mo instead in the same apparatus and bombarding it with a high-energy bombarding gas of argon (Ar) or the like ionized and accelerated for that purpose.
Especially, the invention renders it possible to form a diamond-like film on the shaped surface of a mold substrate consisting of an inexpensive hardened steel, with a firm bond between the diamond-like protective film and the shaped surface of the mold substrate, by the effect of bombardment with Ar or other similar gas, or preferably by the interposition of an Mo-intermediate layer. Since ionization evaporation does not heat the substrate above 520° C. during the process, the working temperature can be fixed low depending on the annealing temperature of the hardened steel as the substrate. Hence there is no possibility of a metallic mold of hardened steel undergoing a decrease of hardness due to unintentional annealing.
Ionization evaporation in a process for forming a diamond-like thin film which comprises ionizing a hydrocarbon feed gas or a feed gas capable of giving a hydrocarbon upon decomposition or reaction by ionization means, such as arc discharge or thermionic emission between a thermionic cathode filament unit and an anode, and accelerating the resulting ion beam with an electric field and directing it toward a substrate to form a diamond-like thin film thereon. (The term "hydrocarbon" as used herein means a saturated hydrocarbon, such as methane, ethane, or propane, or an unsaturated hydrocarbon, such as ethylene, propylene, or acetylene, etc. The "feed gas capable of giving a hydrocarbon upon decomposition" is, e.g., an alcohol, such as methyl alcohol or ethyl alcohol, or a ketone, such as acetone or methyl ethyl ketone. The "feed gas capable of giving a hydrocarbon upon reaction" is, e.g., carbon monoxide and a mixed gas of carbon dioxide and hydrogen. Such a feed gas may contain at least one chosen from among rare gases, such as helium, neon, and argon, or from among hydrogen, oxygen, nitrogen, water, carbon monoxide, carbon dioxide, etc.) As described in patent application Ser. No. 214913/1989, ionization evaporation does not require such a high substrate temperature of 700° C. or above as is necessary in conventional deposition processes ((refer, e.g., to HYOMEN KAGAKU (Surface Chemistry), vol. 5, No. 108 (1984), pp. 108-115 "Various methods"). It is an outstanding process for forming a diamond-like film with high efficiency, the product having good surface properties and high hardness, thermal conductivity, and refractive index. Among other advantages is the nonnecessity of surface finish.
There is shown in FIG. 1 an apparatus for forming an Mo-intermediate layer and a diamond-like film, as a preferred embodiment of the invention. The numeral 30 designates a vacuum vessel and 31 a chamber communicated with an evacuation system 38 to be evacuated up to a high vacuum of about 10-6 Torr. An electrode 32 is located at the back of a substrate (or an article to be protected) S and kept at a negative potential Va. (The substrate, if metallic, may be utilized itself as the electrode.) A mask 42 is provided close to or in contact with the front surface of the substrate S, with a window for controlling the size and shape of the diamond-like thin film to be formed. While the mask may be in contact with the substrate, it is preferably located away from the latter so as to reduce the peripheral thickness of the film and decrease the possibility of cracking. Indicated at 33 is a grid made of Mo and supplied with the same negative potential Va as is the substrate so as to be used in accelerating the hydrocarbon ions during the film-forming process. To enhance the continuity of the film, and smoothen its surface, the grid 33 to be used has a properly chosen porosity (the total area of openings per unit area) and opening density (the number of openings per unit length). It may be equipped with means for causing planar vibrations. A thermionic cathode filament unit 34, kept at a negative potential Vd, is heated by a current If from an AC source to emit thermions. The numeral 35 indicates an inlet for the hydrocarbon feed gas and for bombarding gas such as argon. An anode 36 surrounds the filament unit 34. The anode, while being grounded in this case, maintains a voltage positive to the filament unit and is given a positive potential for the electrode 32 and grid 33. A solenoid 39 is disposed around the filament unit 34, anode 36, and feed inlet 35 so as to be excited by a current Ic from a power supply Vc to produce a magnetic field for the containment of ionized gas. Thus, the formation of the Mo-intermediate layer and diamond-like protective film can be controlled through the adjustments of If, Vd, Va, solenoid current Ic, and ionizing current Ia.
FIG. 3 is a perspective representation of a portion of the apparatus as seen in the direction of arrows A--A in FIG. 1. Where a rectangularly shaped film is to be formed, e.g., an assembly of a plurality of filaments as shown is used or, alternatively, a single filament coil is employed. When a large-area film is to be obtained, it is possible to feed a substance of a corresponding length at a low speed or cause an ion beam to scan at an accordingly reduced speed. Turning to FIG. 1, a line 37 for introducing the hydrocarbon feed gas is formed with a plasma-exciting chamber 37', whereby the efficiency of the ionizing means is enhanced. For the plasma excitation, e.g., microwave, high-frequency wave (RF wave), radioactive rays, and ultraviolet rays can be utilized.
As a further alternative, it is possible to modify part of the construction of FIG. 1 as shown in FIG. 2, with a magnet 40 of fixed or variable strength located above the filament unit 34 so as to deflect an ion beam in the plasma state. The magnetic field produced by the magnet 40, with the strength fixed or variable, is directed at right angles to the direction in which the ion beam travels. This arrangement gives a deflection angle θ for the desired ion beam, e.g., of CH3 + or CH4 + ions. With a fixed arrangement, ions vastly different in mass from these ions, such as hydrogen ions, are deflected to an even greater angle. Neutral particles and heavy polymeric ions move straight ahead. It then follows that if the mask is located ahead, only highly crystalline ions will deposit on the substrate S.
Forming an Mo film
An Mo-intermediate layer is formed on a slightly adhesive substrate of Fe or its alloy, glass, or ceramics, particularly on a metallic mold substrate of hardened steel, in the following manner. First, the vacuum chamber is evacuated to about 10-6 Torr and a bombarding gas chosen from among argon, nitrogen, hydrogen, helium, neon, etc. is introduced to about 0.1 Torr. The filament unit 34 ionizes the gas, and the grid 33 accelerates the resulting ions, e.g., of argon. The argon ions bombard and clean the surface of the substrate S to improve its adhesiveness while driving Mo off from the grid onto the substrate. The voltages applied to or the currents flown through the individual parts, the molecular weight of the bombarding gas (or the average molecular weight in case of a mixed gas), treating time, etc. serve as necessary controlling factors.
The energy of the bombarding gas is calculated by the formula
molecular weight×Ia (mA)×time (hr)
where molecular weight is that of the bombarding gas, Ia is the ionizing current, and time is the bombardment treating time. It is desirable that the energy satisfy
500<molecular weight×Ia (mA)×time (hr)<800.
If the value is too small, the energy of Mo grid bombardment becomes insufficient, resulting in inadequate Mo film formation. If the value is excessive, other components of the apparatus too are etched and the intrusion of impurities lowers the adhesiveness of the resulting film. Preferably, the energy of bombardment ranges from 500 to 800.
Where the hardened steel surface is to be activated before the Mo bombardment, the energy should be between 50 and less than 500. A grid of Mo, SUS303, W or the like may be used. The binding force of the Mo layer is permissible up to the range where the energy is high. The bombardment and the formation of an intermediate layer are continuously variable, and the provision of an intermediate layer gives good result.
Forming a diamond-like film
The next step of forming a diamond-like protective film starts with the evacuation or the chamber 31 to a vacuum as high as 10-6 Torr. A valve on the gas feed line 37 is manipulated to admit methane gas alone or its mixture with hydrogen gas, or with Ar, He, Ne, or other carrier gas, all at predetermined rates, into the chamber through the inlet 35. With concurrent adjustment of the evacuation system 38, a desired gas pressure, e.g., 10-1 Torr, is secured. Meanwhile, the plurality of thermionic cathode filaments 34 are heated by passage of the AC current If, and the differential potential Vd is applied between the filament unit 34 and the anode 36 to produce a discharge. Methane gas or other hydrocarbon fed via the inlet 35 is thermally decomposed and collides with the thermions from the filaments to give positive ions and electrons. The electrons, in turn, collide with other thermally decomposed particles. This phenomenon is repeated under the containment action by the magnetic field of the solenoid until the methane gas is totally converted to positive ions of the thermally decomposed substance.
The positive ions are attracted by the negative potential Va applied to the electrode 32 and the grid 36 and accelerated toward the shaped surface of the substrate S. They thus impinge on the substrate surface of the metallic mold and, through a film-forming reaction, produces a diamond-like protective film thereon. When desired, a thin film of better quality can be obtained using the above-mentioned fixed magnet. The thickness of the film so formed ranges from 0.1 to 100 μm, and in the case of a metallic mold, preferably from 0.5 to 100 μm, more preferably from 1 to 50 μm. If the thickness is less than the general range, the wear resistance and other beneficial effects are reduced. If it exceeds the range no more improvements are attained while the manufacturing time has to be extended. The hardness of the diamond-like thin film is at least 5000 kg/mm2, preferably at least 6000 kg/mm2. Thus, "diamond-like thin film" having a hardness of 5000 kg/mm2 or more is preferably produced by ionization evaporation.
The apparatus shown in FIG. 1 was used and a piece of steel plate SKS2 or SKD11 was placed as a substrate S in the vacuum vessel 30. At a distance of about 6.0 mm downwardly from the substrate surface was hold a grid 33 of Mo, W, or SUS303. The distance between the substrate S and the anode was about 40 mm. Each grid 33 had an opening density of 60 openings per 25.4 mm and a porosity of 41%.
Forming Mo films: The vacuum vessel 30 was evacuated to 10-6 Torr and Ar and H2 gases were introduced. At a gas pressure of 0.1 Torr the thermionic cathode filament unit 34 was caused to discharge. The magnetic flux density of the solenoid 39 was fixed to 400 Gs, the substrate voltage and grid voltage Va to -300 V, and the substrate temperature to 200° C. A current If of 20 A was flown through the filament unit 34. The filament voltage Vd was set to -10 V with variable Ia. The filament unit 34 was in the form of a coil 3 mm wide, and the gap between the coil and the electrode 36 surrounding it was 8 mm. The grid was vibrated at the rate of 5 mm/min.
Forming a diamond-like protective film: The Ar supply was shut off, the vacuum vessel 30 was evacuated to 10-6 Torr, and methane gas was introduced to a gas pressure of 10-1 Torr, when the thermionic cathode filament 34 was caused to discharge. The magnetic flux density of the solenoid 39 was fixed to 400 Gs, the substrate voltage Va to -300 V, and the substrate temperature to 200° C. A current If of 25 A was flown through the filament unit 34.
The filament unit 34 was in the form of a coil 3 mm wide, and the gap between the coil and the electrode 36 surrounding it was 8 mm. The grid was vibrated at the rate of 5 mm/min.
Under the conditions of the filament voltage Vd=-30 V and Vc=30 V, a 1.0 μm-thick diamond-like film was obtained.
The films thus obtained were tested for their adhesion strength and scratch hardness values under microscopic observation. The results are summarized in Table 1. The adhesion strength was determined by bonding a test diamond-like thin film with epoxy resin to a square bar 1 cm square and 10 cm long and then peeling the film from the bar on a tensile tester (marketed under the trade designation "Tensilon"). The scratch hardness was determined by means of a CSR Scratch Tester manufactured by Resca. The results were compared with the standard values or 1.0 each when the treating energy (molecular weight×Ia (A)×time (hr)) was set to 100.
For comparison purposes, the results with grids made of W and steel. SUS303 are also given in the table.
TABLE 1______________________________________Molecular    SKS2              SKD11Grid weight ×            Adhe-   Scratch Adhe- Scratchmate-Ia ×  sion    hard-   sion  hard-rial time        strength                    ness    strength                                  ness______________________________________Mo   100         1.0     1.0     1.0   1.0Ma   600         1.2     2.1     1.3   2.2Mo   1000        0.8     0.6     0.7   0.5W    600         0.5     0.5     0.4   0.2SUS  600         0.3     0.1     0.3   0.1303______________________________________
As can be seen from Table 1: the Ar ion molecular weight×. Ia×time of approximately 600 produces good adhesion strength and scratch hardness. Generally, the value ranges from more than 500 to less than 1000, preferably from more than 500 to less than 800. On the other hand, W gives better results than the ordinary grid material of SUS303 but not as good as Mo does.
The procedure of Example 1 was repeated using a grid of Mo with the exception that a cemented carbide steel was used in addition to SKS2 and SKD11 as metallic mold substrates and the varied treating energies as given in Table 2 were used. The results are shown in Table 2. In the table the "abraded area" is a value obtained by measuring the surface roughness Ra before and after grinding in conformity with the JIS standards and multiplying the difference by the length of scanning. The "scratch hardness" is a relative value measured on the basis of a test piece of SKD11 having a 0.1 μm-thick film treated with an energy of 550.
TABLE 2______________________________________Metallicmold     Molecu-sub-     lar       Film   Vick-strate   weight    thick- ers    Abrad-                                  Scratchmate-    × Ia ×              ness   hard-  ed    hard-rial     time      u      ness   area  ness______________________________________SKD 11   550       0.1    7000   40    1.0and      550       0.6    7000   20    1.5diamond- 550       5.0    7000   20    1.6like     550       5.0    3000   50    0.8thin     550       5.0    6000   20    1.6film     650       5.0    7000   18    2.2    550       25     7000   20    1.7    550       100    7000   20    1.7SKD 11   --        --      800   500   --Cemented --        --     1800   180   --carbidesteel______________________________________
As Table 2 clearly indicates, the use of an Mo grid gives good adhesion strength and scratch hardness upon treatment with an energy of Ar ion molecular weight×Ia×time=about 550 to 650. Both the hardened steel SKD11 and cemented carbide steel showed low degrees of hardness.
The present invention successfully manufactures articles having a diamond-like protective thin film which binds firmly to the substrate by means of an apparatus for forming a diamond-like film by ionization evaporation onto the substrate to be protected, especially a metallic mold, in which an electric field-applying grid to accelerate the ions of an ionized hydrocarbon is built of Mo and it is bombarded by a high-energy bombarding gas produced by ionizing argon (Ar) or the like and accelerating the resulting ions, whereby an Mo film is formed on the substrate and thence a diamond-like thin film is formed on the Mo film. According to the invention, the substrate is not limited to metals; the films can also be formed on such electrically insulating substrates as glass and ceramics without difficulty.
The invention thus uses an apparatus for performing ionization evaporation and bombards the shaped surface of a metallic mold substrate of hardened steel to be protected, with a high-energy bombarding gas formed by ionizing argon or the like and accelerating the resulting ions by an electric field-applying grid, thereby activating the shaped surface of the metallic mold substrate, or using a grid of Mo and forming a Mo film an the substrate surface, and further forming a diamond-like thin film thereon. In this way a metallic mold substrate having a diamond-like protective thin film formed thereon as solidly bound to the substrate surface can be obtained. The metallic mold thus obtained in accordance with the invention is an inexpensive mold which exhibits high performance despite the use of a hardened steel, a material of rather inferior properties, as the substrate.
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metallic substratesUS20040235405 *Sep 19, 2003Nov 25, 2004Chien-Min SungCast diamond tools and formation thereof by chemical vapor depositionUS20050112231 *Nov 26, 2003May 26, 2005Mold-Masters LimitedInjection molding nozzle with wear-resistant tip having diamond-type coatingUS20060093693 *Nov 1, 2005May 4, 2006Towo Corporation Japan Fine Ceramics CenterLow-adhesion material and mold for molding resin using the sameUS20060147631 *Jan 4, 2005Jul 6, 2006Lev Leonid CMethod for making diamond coated substrates, articles made therefrom, and method of drillingUS20060289293 *May 24, 2006Dec 28, 2006Hon Hai Precision Industry Co., Ltd.Composite mold and method for manufacturing the sameUS20080087891 *Oct 22, 2007Apr 17, 2008Chien-Min SungSemiconductor-on-diamond devices and methods of formingUS20110008532 *Dec 19, 2008Jan 13, 2011Mold-Masters (2007) LimitedMethod of manufacturing hot-runner component and hot-runner components thereofUS20110045124 *Sep 19, 2008Feb 24, 2011Mold-Masters (2007) LimitedInjection Molding Nozzle Having A Nozzle Tip With Diamond CrownEP0841140A2 *Nov 10, 1997May 13, 1998Bae Hyeock ChunMethod of enhancing releasing effect of mould using low temperature plasma processesEP0841140A3 *Nov 10, 1997Feb 23, 2000Dong Lyun ChoMethod of enhancing releasing effect of mould using low temperature plasma processesEP1086797A1 *Mar 6, 2000Mar 28, 2001Citizen Watch Co., Ltd.Resin molding mold and method of forming hard coat on resin molding moldEP1086797A4 *Mar 6, 2000Aug 8, 2001Citizen Watch Co LtdResin molding mold and method of forming hard coat on resin molding mold* Cited by examinerClassifications U.S. Classification428/408, 428/432, 428/655, 428/469, 428/678, 249/114.1, 428/660, 249/134, 428/457, 428/663, 249/135, 428/664, 428/661International ClassificationB29C33/56Cooperative ClassificationY10T428/31678, Y10T428/12812, Y10T428/12931, Y10T428/12826, Y10T428/12806, Y10T428/12833, Y10T428/30, B29C33/56, Y10T428/12771European ClassificationB29C33/56Legal 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Site Map Web Part for Microsoft Office SharePoint Server (MOSS) - CodeProject ×
11,264,474 members (21,753 online)
.NET2.0VS2008C#ASP.NETJavascriptXMLWindowsDevIntermediate Related Articles
Site Map Web Part for Microsoft Office SharePoint Server (MOSS) Stephen Huen, 28 Jul 2010
4.18/5 - 7 votesμ 4.18, σa 2.93 [?]
Displays the site structure in a hierarchical tree that is expandable and collapsible.	Download source files - 89.2 KB
SolutionId="SolutionGuid" ResetWebServer="TRUE">
<Assembly Location="QuestechSystems.SharePoint.Publishing.SiteMapWebPart.dll"
<ClassResource Location="images\node-closed.gif" />
<ClassResource Location="images\node-open.gif" />
<ClassResource Location="images\node.gif" />
<FeatureManifest Location="QuestechSiteMapWebPart\Feature.xml" />
Error :- A Web Part or Web Control can not be import in this page. type is not a safe control Gaurav12227-Dec-11 19:52 Giving me a alert error message !!!!!!!!!!!!! Below :----
No site map on a Publishing site with Custom Master page BlueSky2013-Apr-11 7:07 Hi,
Looks like I need some suggestion making the web part to work in my Publishing portal (it works in collaboration sites). The deployment went well - for the webpart configuration section I have 'CurrentNavSiteMapProvider' and added Starting Site URL. Also I tried changing Maximum levels. Nothing shows up for the site map? I have custom Master page and CSS applied for this site. I can see we are referencing 'CurrentNavSiteMapProvider' from both Web.config and Master page. Is there anything I am missing? I sense it's the similar issue why I could not get the OOB Tree view to work in the publishing site when I've our Custom Master page applied. Any suggestions on what should I be looking for on the Custom Master Page would be greatly appreciated. Thank you!
Re: No site map on a Publishing site with Custom Master page BlueSky2015-Apr-11 4:45 Just an update to this issue - does not look like the issue is related to the custom master page or style sheets. I tried changing the master page to 'default.master' and CSS to WSS defaults with no luck. Now my question is whether this web part works with Publishing portal? Can anyone please confirm? Many thanks in advanced!
Quick Launch disappears tjohn434321-Feb-11 11:19 Hello,
Site Map Performance jumbojum30-Apr-10 8:05 Is it possible to make it faster? I have tested in my environment, it took more than 45 second to load.
Path to images cannot be served because it has .SiteMap in it mkamoski11-Mar-10 5:44 All -- Please help. This is the link to the image when I use the control with its default settings... http://www.MySite.org/admin/_wpresources/QuestechSystems.SharePoint.Publishing.SiteMap/1.0.0.0__452af7a31a63d586/images/node.gif ...and this portion of the path... QuestechSystems.SharePoint.Publishing.SiteMap ...causes SharePoint to complain because it sees the folder ending in ".SiteMap" and says "this type of file cannot be served". That is, the extension ".SiteMap" is a reserved extension in DotNet. Too bad you didn't call it "QuestechSystems.SharePoint.Publishing.SiteMapWp" or something similar. How can this be fixed? Please advise. (Otherwise, it is a great control.) Thank you. -- Mark Kamoski
Re: Path to images cannot be served because it has .SiteMap in it Stephen Huen15-Mar-10 14:26 The web part has been updated to resolve the issue. Please give it a try. Thanks.
Anonymous user problem Member 353936128-Dec-09 0:07 Hi,
Doesn't have indentation Member 449799126-Jul-09 8:15 not a tree view, just a flat list
Re: Doesn't have indentation Curtis Shirley28-Aug-09 8:32 Same Issue with indentation here. Only showing a flat list for me.
Ineed to localized to another language Member 206710615-Jul-09 6:17 Ineed to localized to another language
Broken images cheong69@yahoo.com19-Jun-09 16:52 I found that all gifs (node*.gif) are unable to show.
and the URL of image is http://machine_name/SiteDirectory/_wpresources/QuestechSystems.SharePoint.Publishing.SiteMap/1.0.0.0__452af7a31a63d586/images/node.gif
Re: Broken images Stephen Huen29-Jun-09 14:08 I was not able to reproduce the problem. If you hit http://machine_name/SiteDirectory/_wpresources/QuestechSystems.SharePoint.Publishing.SiteMap/1.0.0.0__452af7a31a63d586/images/node.gif in the browser, do you get a 404?
Re: Broken images cheong69@yahoo.com5-Jul-09 16:24 Not 404 error.
Re: Broken images Stephen Huen7-Jul-09 18:05 Looks like something to do with your IIS/ASP.Net configuration. May be article http://support.microsoft.com/kb/815152 will help.
Re: Broken images Member 465313027-Jul-09 6:35 I'm having similar issues, and the article was unhelpful.
Re: Broken images 4wildkat2-Oct-09 6:40 I'm having exactly the same problem and the kb article didn't help me either.
Re: Broken images charmingbalu26-Oct-09 2:18 I have also got the same problem. I have used Team site templates to create my sites. It does show the image, the source of the image is like "http :// SITE /_wpresources/QuestechSystems.SharePoint.Publishing.SiteMap/1.0.0.0__452af7a31a63d586/images/node-open.gif"
Publishing as well as non publishing websites .Netter30-Jan-09 4:51 This is a great webpart but it displays only the publishing sites. It does not display the team sites along with the publishing sites. Is there any way or any code change so that this webpart displays both publishing as well as non publishing website in the site map. Any idea would be highly appreciated.
Deep Down kundankoman22-Jan-09 8:43 Thanks for the wonderful solution. I was just curious if we can go mor deep down . If I have Folder on the shared document , showing the folder and sub folder as well like in tree view if Sharepoint
"Cannot import this webpart" RickyTH3-Nov-08 22:05 Does anyone know on how to solve the problem when trying to add this webpart into the webpart zone and it gives the error saying that "Cannot import this webpart". I really need to use this webpart. Thank you in advance. :(
Css class lattelis11-Jun-08 3:30 Hi,
Thanks Re: Css class MuhammadOmerZubair23-Mar-11 16:08 Hi,
Re: Css class MuhammadOmerZubair23-Mar-11 20:44 Ok guys found the solution. You can use the code below to add your CSS file.
Unable to open the solution sunil_limje3-May-08 2:09 Hi
Thanks in advance. Re: Unable to open the solution Stephen Huen4-May-08 7:15 Do you have Visual Studio 2005 ***SP1*** installed? SP1 supports the Web Application project type. Re: Unable to open the solution sunil_limje5-May-08 0:40 Hi
Still the problem is same. Re: Unable to open the solution Stephen Huen5-May-08 7:06 What edition of Visual Studio 2005 do you have ? Re: Unable to open the solution sunil_limje6-May-08 22:17 I am having Visual studio 2005 team edition for software developers version 8.0.50727.42. Please give me any link to download sp1 if you have. Re: Unable to open the solution Stephen Huen7-May-08 7:39 I am not sure why. The SP1 link, http://www.microsoft.com/downloads/details.aspx?familyid=bb4a75ab-e2d4-4c96-b39d-37baf6b5b1dc&displaylang=en, seems right but it indicates version 50727.762 while you have 50727.42. My suggestion is for you to reinstall it. Licence terms? Antti802-Apr-08 2:30 What are the license terms for this web part? I wasn't able to find anything inside the package nor on this page. Invalid SiteMapProvider: SiteMapDataSource1 Henrik Weimenhog2-Mar-08 23:35 Hi,eventually I almost got it working. I tried to connect my new control to the existing sitemap data source, but I get the following error: Invalid SiteMapProvider: SiteMapDataSource1 Does anyone know what I am doing wrong here? (btw, SharePoint Designer does not recognize my <DW: tag.. is that normal?) My markup looks like this: <%@ Register TagPrefix="DW" Namespace="QuestechSystems.SharePoint.Publishing.WebControls" Assembly="VerticalNavigation, Version=1.0.0.0, Culture=neutral, PublicKeyToken=d6a60c3d38efc327" %>...<DW:VerticalNavigation runat="server" IncludePages="true" IncludeSubSites="true" SiteMapProvider="SiteMapDataSource1"></DW:VerticalNavigation> <PublishingNavigation:PortalSiteMapDataSource ID="siteMapDataSource1" Runat="server" SiteMapProvider="CombinedNavSiteMapProvider" EnableViewState="true" StartFromCurrentNode="true" StartingNodeOffset="0" ShowStartingNode="false" TreatStartingNodeAsCurrent="true" TrimNonCurrentTypes="Heading"/> Re: Invalid SiteMapProvider: SiteMapDataSource1 Stephen Huen10-Mar-08 13:40 You don't need the <PublishingNavigation:PortalSiteMapDataSource ..> tag How to carlosfocker23-Jan-08 9:27 I'm not sure where to start with this. You say I need to compile the code first before I use it in a solution. What type of VS.NET project do I use to compile it? Where is the QuestechSystems.SharePoint.Publishing.dll that is referenced in the manifest.xml and the ddf file? Do I put the images in the solution package? A step by step would greatly improve this page. Build error SharePointBloke17-Jan-08 14:33 When I build the project I get the error:
What am I missing? Re: Build error SharePointBloke17-Jan-08 23:57 I've found that when I add the resources.resx and resources.designer.cs files to the project through the project properties, the resources.designer.cs file changes. Any ideas why this happens? Re: Build error SharePointBloke18-Jan-08 0:17 I overwrote resources.designer.cs with the original source in the project and that seems to have fixed the original problem. However, now I'm getting a different error while compiling:
'QuestechSystems.SharePoint.Publishing.Resources.Resources' does not contain a definition for 'MsgInvalidSiteMapProvider'	C:\Dev\SiteMapWebPart\SiteMapWebPart\WebControls\WebParts\SiteMap\SiteMapWebPart.cs	276	79	SiteMapWebPart Webpart Error GregS4427-Nov-07 13:04 I got the webpart loaded and onto a page but when I try to edit the webpart properties by choosing "Modify Shared Webpart" it gives me an error. Could not find any resources appropriate for the specified culture or the neutral culture. Make sure "SiteMapWebPart.Resources.Resources.resources" was correctly embedded or linked into assembly "SiteMapWebPart" at compile time, or that all the satellite assemblies required are loadable and fully signed. Any ideas? Re: Webpart Error Stephen Huen7-Nov-07 13:19 Is Resources.resx set as Embedded Resource in Visual Studio? Re: Webpart Error GregS4427-Nov-07 14:33 I thought I had added all the files but I guess not. Now that I have added the resx file and the cs file it is giving me this error when I try to build the solution:
internal class Resources { Re: Webpart Error Stephen Huen7-Nov-07 22:29 Try delete all Resources*.*. Add a new resource file in Visual Studio and name it Resources(.resx). Open Resources.resx in the package and copy all the entries over. Re: Webpart Error GregS4428-Nov-07 8:59 I tried that and still get the same error. I added a resources.resx file, copied over your entries and copied over the designer.cs code and it compiled just fine but when I try to edit the web part I get the same error.
For some reason it is not recognizing the resource file. Re: Webpart Error Stephen Huen8-Nov-07 9:19 What is your VS project file structure, namespace and assembly name? Re: Webpart Error GregS4428-Nov-07 9:35 Assembly name: SiteMapWebPart
I basically just copied the files you included over to my project so it looks like that. I can show you a screenshot if you'd like. Solution file Richard Fennell1-Oct-07 4:40 I have downloaded the zip for this project and see that it does not contain the DLL or a solution file to allow me to build the DLL with suitable resource files.
Re: Solution file Stephen Huen1-Oct-07 5:52 No but the zip file should contain all the source files necessary to build the dll and solution file. Re: Solution file Antonio Baros Afonso8-Dec-07 8:04 Can you be more specific? Antonio Afonso
install cowdogs25-Sep-07 4:01 I have installed Package, but i can't find Site Map web part. I have runned InstallPackage.bat file, what I must do now, if I want use Site map web part? Re: install Stephen Huen25-Sep-07 9:19 The InstallPackage.bat is an sample file for building and deploying the Solution package. It relies on a compiled dll. You will need to compile the sample files within your Visual Studio project first. Sites Node on Site Map lunarsolarstar30-Jul-07 6:27 I noticed that the screen shot has a Sites node. Is it correct to think that this node contains all the Sites and Workspaces under the start node? For some reason this node is not visible in the web part and I am unable to find a corresponding option for it. donna
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Patent Citations (63), Non-Patent Citations (2), Referenced by (16), Classifications (9), Legal Events (4)
JP20040319756A * Title not available
CN106238984A * Aug 8, 2016 Dec 21, 2016 徐州工程学院 Horizontal sliding rail-type pose self-adjusting welding machine and control method thereof


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Amazon.com: Double Wide: CDs & Vinyl
CDs & VinylPrime MusicDigital MusicNew ReleasesPre-ordersVinyl RecordsBest SellersToday's DealsAutoRipAdvanced SearchYour Music Library 1-12 of 244 results for CDs & Vinyl : "Double Wide"
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Double Wide2000by Uncle KrackerAudio CD$6.99Only 9 left in stock - order soon.More Buying Choices$0.01used & new(262 offers)
96FREE Shipping on orders over $35Includes FREE MP3 version of this albumSee Detailseligible and 2 more promotionsFREE Shipping on orders over $35Southside Double - Wide: Acoustic Live (Bonus Dvd)2003 | Extra tracksby SevendustAudio CD$19.70Only 4 left in stock - order soon.More Buying Choices$5.66used & new(39 offers)
45FREE Shipping on orders over $35Includes FREE MP3 version of this albumSee Detailseligible and 2 more promotionsTrade-in eligible for an Amazon gift cardFREE Shipping on orders over $35The Best of Jeff Foxworthy: Double Wide Single Minded (CD & DVD)2003 | Original recording remasteredby Jeff FoxworthyAudio CD$10.49Only 1 left in stock - order soon.More Buying Choices$0.01used & new(61 offers)
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Amazon.com: T. Scott "T Scott"'s review of My Pillow Pets Nutty Elephant - Large (Gre...
Luv It, April 29, 2011
By T. Scott "T Scott"
This review is from: My Pillow Pets Nutty Elephant - Large (Grey with Blue) (Toy)
Nutty the elephant is adorable. My son has several pillow pets and I bought this one for myself. Nutty is so cute and now my son has added him to his collection :)
My Pillow Pets Nutty Elephant - Large (Grey with Blue) B00286CY2G
T. Scott "T Scott"
Top Reviewer Ranking: 856,700


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Garmin nuvi 52 5" Sat Nav with UK and Ireland Maps: Amazon.co.uk: Electronics
Lifetime UK and Ireland Maps
Lifetime UK, Ireland and W. Europe Maps
Bright 5" touchscreen sat nav with preloaded street maps of UK and IrelandLane assist and junction view provide guidance at tricky junctionsDisplays speed limit, safety cameras and accurate arrival timeEasily find addresses and millions of points of interest and "Where Am I?" emergency locator tells you of your coordinates and the nearest address, intersection, hospitals, police and fuel stationsIncludes microSD card slot to accommodate map updates and additional map options Frequently Bought Together
This item: Garmin nuvi 52 5" Sat Nav with UK and Ireland Maps £70.00
Garmin Universal 5 inch Soft Carrying Case for Satellite Navigator £5.79
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Garmin Universal 5 inch Soft Carrying Case for Satellite Navigator 4.2 out of 5 stars (78)
In Car Charger Cable For Garmin Nuvi 2598LMT-D 2797LMT 2597LMT 2597LM 12v or 24v Power Lead 3.7 out of 5 stars (9)
Neotechs® 5" Sat Nav Hard Carry Case For Garmin Nuvi 52 52LM 54 54LM 4.6 out of 5 stars (28)
Garmin USB / PC Cable for Garmin nuvi and zumo Sat Navs 3.8 out of 5 stars (212)
UK Mains Home Travel AC Charger For Garmin Nuvi 2598LMT-D 2597LMT 2597LM Sat Nav GPS 4.2 out of 5 stars (9)
B005HN1UIG,B00D2UWT72,B00E5YXL6M,B000LRMS66,B000BM8RFM,B00D2UW93Q,B00D2UW4XQ,B002LJVIY0,B00E0403IG,B00D2UWF76,B005O69C0O,B0076LNQPW,B00BST8U68,B00I9X5VBI,B0076LP6AU,B00A3BBYLK,B003BZYWPK,B009OZNELO,B003Y79H5A,B004OXXZOW,B007EN5MH2,B0098LLNJY,B0076LMLK8,B0047CVO70,B001EGP3RY,B003LNLPQ6,B000KN6L9G,0717663396,B006O8AY7Q,B004DBHR2Q,B001EHF3OG
Style Name: UK and Ireland Maps
Looking for a case to fit your new sat nav? Check out the AmazonBasics GPS Travel Case, from our AmazonBasics bags and cases range, a new offering of quality consumer electronics accessories at great value prices. Available Warranties for This Item Style Name: UK and Ireland Maps
Product Dimensions: 8.6 x 2 x 13.9 cm ; 181 g
Item model number: 010-01115-10
ASIN: B00FKP2I00
Amazon Bestsellers Rank: 351 in Electronics (See Top 100 in Electronics)
#10 in Electronics > Car & Vehicle Electronics > GPS Devices > Sat Navs
Garmin nuvi 52 UK 5" Sat Nav with UK and Ireland Maps An Essential Sat Nav For Simple And Safe Navigation With its bright 5-inch display and spoken turn-by-turn directions, nüvi 52 is an easy-to-use, dedicated sat nav that helps you get to your destination easily. It comes with speed camera alerts as well as Lane Assist and Junction View for simple and safe navigation so you don’t get lost. Detailed Maps nüvi 52 arrives loaded with detailed maps of the UK and Ireland and thousands of Points of Interest (POIs) such as restaurants, businesses and shops. To find an address or POI simply search for it on your nüvi and press ‘Go’ to be directed there with turn-by-turn instructions and spoken street names for extra clarity. You also have the ability to add custom POIs so you can find your favourite locations easily again and again. Clear guidance at junctions Diving Guidance You See and Hear Avoid confusion at tricky exits and junctions. Lane Assist guides you into the correct lane for approaching turns and exits, and Junction View displays an onscreen image of the upcoming junction so you know what to expect before you reach the junction. The split screen mode shows your position on the map alongside a realistic depiction of your upcoming manoeuvre. Information at a Glance nüvi 52 displays speed limit, current speed and accurate time of arrival. With a quick glance, you can read the name of your current street. With safety camera alerts Keep an Eye on the Latest Speed and Safety Cameras with Safety Camera Alerts nüvi 52 contains Garmin’s Cyclops Safety Camera system, for real-time, direction-relevant and accurate alerts. The full safety camera database is already pre-loaded on your sat nav. However, you can get regular or one-off updates to ensure you’ve always got the latest camera locations, so you can drive safety and legally. Where Am I? The Where am I? Emergency locator is a safety feature that can be very helpful if you break down or need a local service urgently. Simply tap the car icon on the map screen to get your exact coordinates, address and junction, contact details for vehicle recovery services and directions to your nearest hospitals, police and petrol stations. This can also be used to save your current location so you can find your way back there again easily in the future. One-stop Device Management Use Gamin Express online to keep your nüvi up-to-date. Garmin Express makes it easy to update maps and software, transfer favourites to and from devices, and install free custom vehicles and voices. Compare Garmin Sat Navs Garmin Nuvi 42LM 4.3" Sat Nav with UK and Ireland Maps and Free Lifetime Map Updates Garmin nuvi 52 5" Sat Nav with UK and Ireland Maps Garmin nuvi 52 5" Sat Nav with UK and Western Europe Maps Garmin nuvi 52 LM 5" Sat Nav With UK and Ireland Maps and Free Lifetime Map Updates Garmin nuvi 52LM 5" Sat Nav with UK and Western Europe Maps and Free Lifetime Map Updates Garmin nuvi 52LM 5" Sat Nav with UK and Western Europe Maps and Free Lifetime Map Updates Screen Size 4.3" 5" 5" 5" 5" 6" Map Coverage UK/ROI UK/ROI UK/ROI and Western Europe UK/ROI UK/ROI and Western Europe UK/ROI Free Lifetime Map Updates Yes Yes Yes Yes Lane Assist Yes Yes Yes Yes Yes Yes Junction View Yes Yes Yes Yes Yes Yes Up Ahead Points of Interest Yes Dual Orientation Manual Manual Manual Manual Manual Manual Product Description
Nuvi 52 UK and Ireland 5" Sat Nav
Garmin nuvi 50 5" Sat Nav with UK and Ireland Maps 4.3 out of 5 stars (452)
Garmin nuvi 2595LMT 5" Sat Nav with UK and Full Europe Maps, Free Lifetime Map Updates and Free Lifetime  4.0 out of 5 stars (1,012)
TomTom Start 25 M Sat Nav with UK Maps & Lifetime Map Updates 4.0 out of 5 stars (485)
1411506274
12 of 12 people found the following review helpfulFor a budget Sat Nav it does the job pretty well
#1 REVIEWER#1 HALL OF FAME on 8 Sep 2014Style Name: UK and Ireland Maps
This is mostly a cosmetic update to the Nuvi 50 model the features are very much the same as the older model, screen and features are the same just a nicer case; some of the higher end features are missing so don't expect all the bells and whistles of more expensive models, but it's certainly decent value for money and a good choice for new users or folks looking for a simple easy to use device.Read more ›
6 of 6 people found the following review helpfulNice unit and software - no USB lead
VINE VOICE on 21 Aug 2014Style Name: UK and Ireland Maps
30 of 32 people found the following review helpfulGood but not exceptional
TOP 500 REVIEWERVINE VOICE on 22 Aug 2014Style Name: UK and Ireland Maps
Comments are based on using a Nuvi 52 extensively for three weeks last month (came with rental car) and using the test unit itself.This is an entry level model that doesn't look too bad, certainly wouldn't have anyone believing that this is a no frills version.The Nuvi 52 for instance gives you a 5 inch screen, larger than many of the cheapest sat navs on the market. Screen visibility is quite good from all angles although you will need to max out the brightness in strong sunshine. The basic colour choice is best described as garish but you certainly will be able to distinguish between different road types etc!Setup is easy, took a while to first acquire satellites but after that it was quick to fix location on start up. It comes with a windscreen sucker mount that is not the easiest to remove from the unit but this is a basic unit . I would say that the TomTom mounts for comparable devices are however easier to use.Annoyingly , Garmin only gives a power lead permanently wired to a 12v cigarette lighter adaptor. If you want to charge it from the mains or connect to your PC/Mac, you have to source the relevant USB cable yourself. It doesn't use the micro connector either, unlike the majority of devices, but we found we had a portable hard drive lead that did the trick. Oh and an Apple iPhone power adaptor seemed to work happily with the aforesaid lead and the Nuvi 52. Suggestion to Garmin.... supplying a standard USB cable would probably save money and would really give users much more flexibility. Like your major competitors do!The briefest of instructions come with the unit and you have to download a manual should you want it.Read more ›
Good value for money.Bought for use in Italy - worked fine
Published 1 day ago by Dr S T Ball
Excellent value for money. Good clear audio, and voice does not keep on and on repeating itself for every instruction like my last satnav did.
Published 4 days ago by anthony whitburn
pleased with the sat nav very easy to use.
Published 6 days ago by Douglas Cook
GREAT PRODUCT - MUCH MORE VERSATILE THAN THE TON TOM. RECOMMENDED.
Published 8 days ago by Mr. EC Morrow
Confident in the directions given
Very easy to use and good directions, I am confident I will get to where I need to be without a mystery tour.
Published 8 days ago by G R OSULLIVAN
A good product. Easy to set up and use.
Published 8 days ago by T Agius Ferrante
so I can honestly say the service was good and the product is perfect...
My Sat Nav requirements are very straightforward and the Garmin nuvi 52 meets those requirements exactly.
Published 9 days ago by Peter Iles
Garmin nuvi 52 LM 5" Sat Nav with UK and Ireland Maps and Free...
This Sat Nav is brilliant, I have a free app called NAV Free on my iPhone which is functional but not that good especially for here in the Channel Islands whereas with this one I...
Published 11 days ago by nlel1975
but it was a great buy.
Did its job well, rerouted me when roadworks closed roadf, still getting used to it, but it was a great buy..
Published 13 days ago by imagio
I have returned this item twice in two weeks. it is not a satnav, it directs incorrectly and incoherently. Not fit for purpose.Back to a tomtom for me
Published 14 days ago by mrs linda forster


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,500 more cafes over the next 5 years. another 1,500 stores are planned for canada and latin america. starbucks has expansion plans in china and for its product line sold in grocery stores and other vendors. >>> your smartphone will soon be able to send how your feeling and respond proeply. it uses voice features. it was successful about 80% of the time in correctly identifying the emotion. rob, can you tell my emotion right now? >> you sound happy and wide-awake. >> i'm very happy. >> i'm sure that's not the caffeine talking. >>> next, on alert. a popular baby recliner. the focus of a new government warning after the deaths of several kids. >>> and a mystery in arizona. a college student missing. was he a victim of fraternity hazing? >>> plus, what a night for kobe bryant. the incredible feat only four other people have ever done. "this is george. he is a good little monkey and always very curious. one day george got an important letter. he's built a rocket ship to travel into space." google, how far is earth to the moon? the moon is 238,900 miles... "the great moment had come." 3, ×
years. >>> the world's largest company born in america will soon be selling products with the label made in america. bowing to criticism, apple announced it will move production of some mac computers from china back into the u.s. the decision may be more economic with patriotic, with chinese wages on the rise. iphones and ipads will be assembled overseas. >>> and macy's are inviting customers to shop until you drop for the final week of christmas. macy's will be open from 48 hours straight, from december 21st to the 23rd, giving some shoppers much-needed time. if the move pays off for macy's, expect other stores to follow suit. >> good news for procrastinators. >> like you. >> exactly. >>> "fifty shades of grey" is turning into green for random house employees. thanks in part to the hugely popular book and its sequels, every employee from editors to warehouse workers is getting a $5,000 bonus. woo. not bad at all. >> 5,000 shades of grey. >> a lot of satisfied readers. >>> when we come back, baby swap. a careless hospital mixup that has two new mothers fighting mad. >>> and gone from the ×
'll have more from the scene, coming up later today, on "good morning america." >>> we have breaking news now. an overnight manhunt, at cal state fullerton, is over, lasting over 12 hours during the night, after the university went on lockdown. s.w.a.t. teams spent the night looking for two robbery suspects who led police on a wild chase, after holding up a jewelry store and shooting an employee. at least one of the men was spotted in a university building last night. police slowly went door-to-door until giving the all-clear around midnight. during the ordeal, students tweeting pictures from the scene. you could see them in dark classrooms. some using tables and chairs to barricade themselves. the cal state website says things will be back to normal, beginning this morning. >>> well, john mcafee's legal saga has taken another turn this morning. the software pioneer is back in the u.s., after the guatemalan government deported him. mcafee arrived in miami last night and then spoke to reporters from his hotel in south beach. he told abc news that he lost everything in belize, $20 million i ×
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than 200 million guns in all on the streets of america. >>> one group that has been silent since the connecticut shootings has been the gun lobby itself, the national rifle association. the usually social media-savvy nra hasn't tweeted or posted anything on its facebook page since friday. the facebook page was taken down a day after it boasted of reaching 1.7 million likes. >> deafening silence perhaps. >>> coming up, what to tell your children as they go back to school today. >>> and the morning's other news today. signs of progress as we get closer and closer to what seems like big news last week, the fiscal cliff. >>> and kate middleton steps out for the first time since being hospitalized. stay with us. hospitalized. stay wit ♪ ♪ >>> in brookfield, wisconsin, the sikh temple, still reeling from its own mass shooting held a prayer vigil for victims in newtown last night. six people were killed there when a gunman burst into that temple and opened fire last august. >>> unfortunately more gun violence news to bring you this morning. the topeka, kansas, police force is in mou ×
with us for "good morning america" for the very latest on the blizzard. team coverage, live, from the storm zone. >>> and switching gears, now. we have shocking developments from washington overnight. that so-called plan "b," to avoid the fiscal cliff has failed. and president obama is delaying his vacation to hawaii because of the ongoing stalemate. nick ratner has the latest from capitol hill. >> reporter: in a stunning surprise, splits within house republican ranks forced speaker john boehner to cancel a planned vote on his tax cut bill. >> the house will call of the chair. >> reporter: in a statement, speaker boehner said his plan "b" tax bill did not have sufficient support to pass. the speaker said, it's now up to the president to avert the fiscal cliff. boehner, earlier, had said he hoped to revive stalled white house negotiations. >> the president and i are going to have to work together to solve those challenges. >> reporter: many house republicans told party leaders they would not support a bill that violated their no tax hike pledge to raise tax rate, even on millionair ×
>>> making news in america this morning -- >> a powerful and deadly storm slams a huge chunk of the nation. and it's not over yet. snow, rain and wind are causing major destruction. we will let you know what you can expect today. >>> also this morning, a turn for the worse. former president h.w. bush is in doctor's care. what they're saying about his prognosis. >>> plus, twisted luck after a horrible crash. how a jogger jumped into action to help save a man's life. >>> and who says you have to be a kid to get giddy over your gifts? this viral video shows a man's genuine joy. and now, his family is sharing his story. >>> good morning. i'm muhammad lila, in for rob nelson. >> i'm brandi hitt in for paula faris. she's on assignment. we begin with the storm system that is leaving communities covered in snow. the storm is being blamed for six deaths. thousands are without power. and travelers are stranded. a deadly winter storm has dropped massive amounts of snow from arkansas up through the midwest, to illinois and indiana. the powerful system is now a nor'easter, with strong win ×
of the busiest ports in america. a walkout with a multibillion dollar impact around the country. >> 10,000 workers will be back on the job at the ports of los angeles and long beach today, which handle about half the cargo coming into the u.s. an overnight contract agreement ends an eight-day walkoff that kept billions upon billions of dollars in cargo from getting to warehouses nationwide. crucial merchandise in these days before christmas. they estimated it was about $1 billion a day that this strike was going on. >> it's over now. that's the good news out of l.a. this morning. >>> now, we turn to the battle over how to keep the nation from going over that so-called fiscal cliff. the clock is ticking now. 27 days to go. >> and president obama and congressional republicans are making plenty of sound bytes about it all. but very little progress. abc's tahman bradley has the details from washington. >> reporter: democrats and republicans remain light years apart. here's president obama, in an interview with bloomberg tv, describing house speaker john boehner's plan to avoid the fiscal c ×
, abc news. >>> that's what's making news this morning in america this morning. >> stay with us for "good morning america." have a wonderful weekend. ×
>>> making news in america this morning. >> it will be another day of heartbreaking farewells in newtown, connecticut, as four more families prepare to lay to rest their little ones. >>> plus, a mixed message. friday's massacre prompts calls for swift action on gun control. but sales of guns are surging. >>> the wind, the snow, sure signs of the season. a snowstorm is moving across the country, right in time for the holidays. we'll show you where it will hit. >>> and sweet success. a little girl takes on a big company, cracking the glass ceiling for future generations. but it's not who you think. it was all for her little brother. >>> and a good tuesday morning, everyone. a ritual returns for thousands of older students in newtown. they're going back to school today. but those who attended sandy hook elementary are still waiting for their new classrooms. >> and this long line of funerals. very sad days. it continues later today. tahman bradley joins us this morning from newtown. good morning, tahman. >> reporter: good morning, rob and paula. it is remarkable to see this commun ×
>>> making news this morning in america. breaking news. hillary clinton hospitalized. >> the secretary of state wakes up in a new york hospital this morning, being treated for a blood clot. >>> it's down to the deadline. if congress and the president are going try to stop the nation from going over the fiscal cliff. tax hikes and spending cuts are just hours away. >>> despite the looming cliff, party preparations are under way on this new year's eve, as we welcome 2013. >>> and moengs nal and triumphant return to the sidelines. for indianapolis colts coach chuck pagano. seems his inspired season is not over yet. >>> good morning, i'm john muller sitting in for rob nelson. >> and i'm paula faris. >>> it looks like secretary of state hillary clinton will be celebrating the new year from a hospital bed. >> during a routine checkup for an earlier concussion, doctors discovered she had a blood clot. he's abc's dierdre bryant. >> reporter: secretary of state hillary clinton was admitted to the hospital on sunday with a blood clot. her doctors discovered it in a followup exa ×
, of course. that's what's making news in america this morning. >> stay was. have great morning, everybody. captioned by closed captioning services, inc. >>> good morning. home you had a great weekend. >> it was good for what it was worth. >> short but good, thanks for joining us i'm kristen sze. >>> i'm eric thomas. we have weather that is changing. >>> what is going on mike? >>> even though the weekend is over the warm weather will stay around. mild when you step out, ×
days for more behind, should stay low next year, where it is now, less than 1%. >>> america's biggest automaker is putting new attention on some of its biggest vehicles. general motors has released their new silverado and gmc pickup trucks. looking to crash in on the growing demand for full-size trucks. the rebound in housing and construction is helping fuel the strength in truck sales. >>> the iphone 5 finally went on sale today, in the world's biggest smartphone market, china. that country is hugely important to apple, which has seen its stock price slide lately. only the u.s., in fact, buys more apple products. and china accounted for almost $24 billion or about 15% of apple's revenues in the past year. >>> and it's no secret that apple and other tech companies pay well. it turns out even their interns are scoring big bucks at facebook. >> business insider reports facebook pays interns more than $5,600 a month. and that ends up being about $67,000 a year, yep, for being an intern. that's about $25,000 more than the average u.s. worker makes. >> here's your application. and i printe ×
in the darkness. >>> that's what's making news in america this morning. >> thanks for watching, everybody. captioned by closed captioning services, inc. >>> tuesday morning, 4:30 thank you for joining us, i'm kristen sze. >>> and i'm eric thomas. it is not raining. >>> but it is still cold. >> it is a little bit cold. in the 40s in most neighborhoods. check out doppler 7 hd, rather quiet this morning. put away the wet weather gear for the next couple of mornings, we are going to have cool conditions that is Search Results 0 to 28 of about 29 (some duplicates have been removed)

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Words containing campcra | Words that contain campcra
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Words containing campcra
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