thermo/vapor_pressure.py
def Ambrose_Walton(T, Tc, Pc, omega):
    r'''Calculates vapor pressure of a fluid at arbitrary temperatures using a
    CSP relationship by [1]_; requires a chemical's critical temperature and
    acentric factor.

    The vapor pressure is given by:

    .. math::
        \ln P_r=f^{(0)}+\omega f^{(1)}+\omega^2f^{(2)}

        f^{(0)}=\frac{-5.97616\tau + 1.29874\tau^{1.5}- 0.60394\tau^{2.5}
        -1.06841\tau^5}{T_r}

        f^{(1)}=\frac{-5.03365\tau + 1.11505\tau^{1.5}- 5.41217\tau^{2.5}
        -7.46628\tau^5}{T_r}

        f^{(2)}=\frac{-0.64771\tau + 2.41539\tau^{1.5}- 4.26979\tau^{2.5}
        +3.25259\tau^5}{T_r}

        \tau = 1-T_{r}

    Parameters
    ----------
    T : float
        Temperature of fluid [K]
    Tc : float
        Critical temperature of fluid [K]
    Pc : float
        Critical pressure of fluid [Pa]
    omega : float
        Acentric factor [-]

    Returns
    -------
    Psat : float
        Vapor pressure at T [Pa]

    Notes
    -----
    Somewhat more accurate than the :obj:`Lee_Kesler` formulation.

    Examples
    --------
    Example from [2]_; ethylbenzene at 347.25 K.

    >>> Ambrose_Walton(347.25, 617.15, 36.09E5, 0.304)
    13278.878504306222

    References
    ----------
    .. [1] Ambrose, D., and J. Walton. "Vapour Pressures up to Their Critical
       Temperatures of Normal Alkanes and 1-Alkanols." Pure and Applied
       Chemistry 61, no. 8 (1989): 1395-1403. doi:10.1351/pac198961081395.
    .. [2] Poling, Bruce E. The Properties of Gases and Liquids. 5th edition.
       New York: McGraw-Hill Professional, 2000.
    '''
    Tr = T/Tc
    tau = 1 - T/Tc
    f0 = (-5.97616*tau + 1.29874*tau**1.5 - 0.60394*tau**2.5 - 1.06841*tau**5)/Tr
    f1 = (-5.03365*tau + 1.11505*tau**1.5 - 5.41217*tau**2.5 - 7.46628*tau**5)/Tr
    f2 = (-0.64771*tau + 2.41539*tau**1.5 - 4.26979*tau**2.5 + 3.25259*tau**5)/Tr
    return Pc*exp(f0 + omega*f1 + omega**2*f2)
def Ambrose_Walton(T, Tc, Pc, omega):
    r'''Calculates vapor pressure of a fluid at arbitrary temperatures using a
    CSP relationship by [1]_; requires a chemical's critical temperature and
    acentric factor.

    The vapor pressure is given by:

    .. math::
        \ln P_r=f^{(0)}+\omega f^{(1)}+\omega^2f^{(2)}

        f^{(0)}=\frac{-5.97616\tau + 1.29874\tau^{1.5}- 0.60394\tau^{2.5}
        -1.06841\tau^5}{T_r}

        f^{(1)}=\frac{-5.03365\tau + 1.11505\tau^{1.5}- 5.41217\tau^{2.5}
        -7.46628\tau^5}{T_r}

        f^{(2)}=\frac{-0.64771\tau + 2.41539\tau^{1.5}- 4.26979\tau^{2.5}
        +3.25259\tau^5}{T_r}

        \tau = 1-T_{r}

    Parameters
    ----------
    T : float
        Temperature of fluid [K]
    Tc : float
        Critical temperature of fluid [K]
    Pc : float
        Critical pressure of fluid [Pa]
    omega : float
        Acentric factor [-]

    Returns
    -------
    Psat : float
        Vapor pressure at T [Pa]

    Notes
    -----
    Somewhat more accurate than the :obj:`Lee_Kesler` formulation.

    Examples
    --------
    Example from [2]_; ethylbenzene at 347.25 K.

    >>> Ambrose_Walton(347.25, 617.15, 36.09E5, 0.304)
    13278.878504306222

    References
    ----------
    .. [1] Ambrose, D., and J. Walton. "Vapour Pressures up to Their Critical
       Temperatures of Normal Alkanes and 1-Alkanols." Pure and Applied
       Chemistry 61, no. 8 (1989): 1395-1403. doi:10.1351/pac198961081395.
    .. [2] Poling, Bruce E. The Properties of Gases and Liquids. 5th edition.
       New York: McGraw-Hill Professional, 2000.
    '''
    Tr = T/Tc
    tau = 1 - T/Tc
    f0 = (-5.97616*tau + 1.29874*tau**1.5 - 0.60394*tau**2.5 - 1.06841*tau**5)/Tr
    f1 = (-5.03365*tau + 1.11505*tau**1.5 - 5.41217*tau**2.5 - 7.46628*tau**5)/Tr
    f2 = (-0.64771*tau + 2.41539*tau**1.5 - 4.26979*tau**2.5 + 3.25259*tau**5)/Tr
    return Pc*exp(f0 + omega*f1 + omega**2*f2)
def Ambrose_Walton ( T , Tc , Pc , omega ) : Tr = T / Tc tau = 1 - T / Tc f0 = ( - 5.97616 * tau + 1.29874 * tau ** 1.5 - 0.60394 * tau ** 2.5 - 1.06841 * tau ** 5 ) / Tr f1 = ( - 5.03365 * tau + 1.11505 * tau ** 1.5 - 5.41217 * tau ** 2.5 - 7.46628 * tau ** 5 ) / Tr f2 = ( - 0.64771 * tau + 2.41539 * tau ** 1.5 - 4.26979 * tau ** 2.5 + 3.25259 * tau ** 5 ) / Tr return Pc * exp ( f0 + omega * f1 + omega ** 2 * f2 )
r'''Calculates vapor pressure of a fluid at arbitrary temperatures using a
    CSP relationship by [1]_; requires a chemical's critical temperature and
    acentric factor.

    The vapor pressure is given by:

    .. math::
        \ln P_r=f^{(0)}+\omega f^{(1)}+\omega^2f^{(2)}

        f^{(0)}=\frac{-5.97616\tau + 1.29874\tau^{1.5}- 0.60394\tau^{2.5}
        -1.06841\tau^5}{T_r}

        f^{(1)}=\frac{-5.03365\tau + 1.11505\tau^{1.5}- 5.41217\tau^{2.5}
        -7.46628\tau^5}{T_r}

        f^{(2)}=\frac{-0.64771\tau + 2.41539\tau^{1.5}- 4.26979\tau^{2.5}
        +3.25259\tau^5}{T_r}

        \tau = 1-T_{r}

    Parameters
    ----------
    T : float
        Temperature of fluid [K]
    Tc : float
        Critical temperature of fluid [K]
    Pc : float
        Critical pressure of fluid [Pa]
    omega : float
        Acentric factor [-]

    Returns
    -------
    Psat : float
        Vapor pressure at T [Pa]

    Notes
    -----
    Somewhat more accurate than the :obj:`Lee_Kesler` formulation.

    Examples
    --------
    Example from [2]_; ethylbenzene at 347.25 K.

    >>> Ambrose_Walton(347.25, 617.15, 36.09E5, 0.304)
    13278.878504306222

    References
    ----------
    .. [1] Ambrose, D., and J. Walton. "Vapour Pressures up to Their Critical
       Temperatures of Normal Alkanes and 1-Alkanols." Pure and Applied
       Chemistry 61, no. 8 (1989): 1395-1403. doi:10.1351/pac198961081395.
    .. [2] Poling, Bruce E. The Properties of Gases and Liquids. 5th edition.
       New York: McGraw-Hill Professional, 2000.
r Calculates vapor pressure of a fluid at arbitrary temperatures using a CSP relationship by [ 1 ] _ ; requires a chemical s critical temperature and acentric factor .