thermo/phase_change.py
def Pitzer(T, Tc, omega):
    r'''Calculates enthalpy of vaporization at arbitrary temperatures using a
    fit by [2]_ to the work of Pitzer [1]_; requires a chemical's critical
    temperature and acentric factor.

    The enthalpy of vaporization is given by:

    .. math::
        \frac{\Delta_{vap} H}{RT_c}=7.08(1-T_r)^{0.354}+10.95\omega(1-T_r)^{0.456}

    Parameters
    ----------
    T : float
        Temperature of fluid [K]
    Tc : float
        Critical temperature of fluid [K]
    omega : float
        Acentric factor [-]

    Returns
    -------
    Hvap : float
        Enthalpy of vaporization, [J/mol]

    Notes
    -----
    This equation is listed in [3]_, page 2-487 as method #2 for estimating
    Hvap. This cites [2]_.

    The recommended range is 0.6 to 1 Tr. Users should expect up to 5% error.
    T must be under Tc, or an exception is raised.

    The original article has been reviewed and found to have a set of tabulated
    values which could be used instead of the fit function to provide additional
    accuracy.

    Examples
    --------
    Example as in [3]_, p2-487; exp: 37.51 kJ/mol

    >>> Pitzer(452, 645.6, 0.35017)
    36696.736640106414

    References
    ----------
    .. [1] Pitzer, Kenneth S. "The Volumetric and Thermodynamic Properties of
       Fluids. I. Theoretical Basis and Virial Coefficients."
       Journal of the American Chemical Society 77, no. 13 (July 1, 1955):
       3427-33. doi:10.1021/ja01618a001
    .. [2] Poling, Bruce E. The Properties of Gases and Liquids. 5th edition.
       New York: McGraw-Hill Professional, 2000.
    .. [3] Green, Don, and Robert Perry. Perry's Chemical Engineers' Handbook,
       Eighth Edition. McGraw-Hill Professional, 2007.
    '''
    Tr = T/Tc
    return R*Tc * (7.08*(1. - Tr)**0.354 + 10.95*omega*(1. - Tr)**0.456)
def Pitzer(T, Tc, omega):
    r'''Calculates enthalpy of vaporization at arbitrary temperatures using a
    fit by [2]_ to the work of Pitzer [1]_; requires a chemical's critical
    temperature and acentric factor.

    The enthalpy of vaporization is given by:

    .. math::
        \frac{\Delta_{vap} H}{RT_c}=7.08(1-T_r)^{0.354}+10.95\omega(1-T_r)^{0.456}

    Parameters
    ----------
    T : float
        Temperature of fluid [K]
    Tc : float
        Critical temperature of fluid [K]
    omega : float
        Acentric factor [-]

    Returns
    -------
    Hvap : float
        Enthalpy of vaporization, [J/mol]

    Notes
    -----
    This equation is listed in [3]_, page 2-487 as method #2 for estimating
    Hvap. This cites [2]_.

    The recommended range is 0.6 to 1 Tr. Users should expect up to 5% error.
    T must be under Tc, or an exception is raised.

    The original article has been reviewed and found to have a set of tabulated
    values which could be used instead of the fit function to provide additional
    accuracy.

    Examples
    --------
    Example as in [3]_, p2-487; exp: 37.51 kJ/mol

    >>> Pitzer(452, 645.6, 0.35017)
    36696.736640106414

    References
    ----------
    .. [1] Pitzer, Kenneth S. "The Volumetric and Thermodynamic Properties of
       Fluids. I. Theoretical Basis and Virial Coefficients."
       Journal of the American Chemical Society 77, no. 13 (July 1, 1955):
       3427-33. doi:10.1021/ja01618a001
    .. [2] Poling, Bruce E. The Properties of Gases and Liquids. 5th edition.
       New York: McGraw-Hill Professional, 2000.
    .. [3] Green, Don, and Robert Perry. Perry's Chemical Engineers' Handbook,
       Eighth Edition. McGraw-Hill Professional, 2007.
    '''
    Tr = T/Tc
    return R*Tc * (7.08*(1. - Tr)**0.354 + 10.95*omega*(1. - Tr)**0.456)
def Pitzer ( T , Tc , omega ) : Tr = T / Tc return R * Tc * ( 7.08 * ( 1. - Tr ) ** 0.354 + 10.95 * omega * ( 1. - Tr ) ** 0.456 )
r'''Calculates enthalpy of vaporization at arbitrary temperatures using a
    fit by [2]_ to the work of Pitzer [1]_; requires a chemical's critical
    temperature and acentric factor.

    The enthalpy of vaporization is given by:

    .. math::
        \frac{\Delta_{vap} H}{RT_c}=7.08(1-T_r)^{0.354}+10.95\omega(1-T_r)^{0.456}

    Parameters
    ----------
    T : float
        Temperature of fluid [K]
    Tc : float
        Critical temperature of fluid [K]
    omega : float
        Acentric factor [-]

    Returns
    -------
    Hvap : float
        Enthalpy of vaporization, [J/mol]

    Notes
    -----
    This equation is listed in [3]_, page 2-487 as method #2 for estimating
    Hvap. This cites [2]_.

    The recommended range is 0.6 to 1 Tr. Users should expect up to 5% error.
    T must be under Tc, or an exception is raised.

    The original article has been reviewed and found to have a set of tabulated
    values which could be used instead of the fit function to provide additional
    accuracy.

    Examples
    --------
    Example as in [3]_, p2-487; exp: 37.51 kJ/mol

    >>> Pitzer(452, 645.6, 0.35017)
    36696.736640106414

    References
    ----------
    .. [1] Pitzer, Kenneth S. "The Volumetric and Thermodynamic Properties of
       Fluids. I. Theoretical Basis and Virial Coefficients."
       Journal of the American Chemical Society 77, no. 13 (July 1, 1955):
       3427-33. doi:10.1021/ja01618a001
    .. [2] Poling, Bruce E. The Properties of Gases and Liquids. 5th edition.
       New York: McGraw-Hill Professional, 2000.
    .. [3] Green, Don, and Robert Perry. Perry's Chemical Engineers' Handbook,
       Eighth Edition. McGraw-Hill Professional, 2007.
r Calculates enthalpy of vaporization at arbitrary temperatures using a fit by [ 2 ] _ to the work of Pitzer [ 1 ] _ ; requires a chemical s critical temperature and acentric factor .