The assumption that black-body radiation is thermal leads to an accurate prediction: the total amount of emitted energy goes up with the temperature according to a definite rule, the Stefan–Boltzmann law (1879–84). But it was also known that the colour of the light given off by a hot object changes with the temperature, so that "white hot" is hotter than "red hot". Nevertheless, Wilhelm Wien discovered the mathematical relationship between the peaks of the curves at different temperatures, by using the principle of adiabatic invariance. At each different temperature, the curve is moved over by Wien's displacement law (1893). Wien also proposed an approximation for the spectrum of the object, which was correct at high frequencies (short wavelength) but not at low frequencies (long wavelength). It still was not clear why the spectrum of a hot object had the form that it has (see diagram).
Who discovered the mathematical relationship between peaks and curves of light at different temperatures?
Wilhelm Wien